Studies in sesquiterpenes-L: 3-hydroxylongifolaldehyde, the elusive intermediate in the abnormal perbenzoic acid oxidation of longifolene

Joshi, A. P.
Nayak, U. R.
Sukh Dev,

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Publication date

January 1976

DOI

10.1016/0040-4020(76)85023-5

Publisher

Elsevier Science

Abstract

The isolation and stereochemistry of 3-hydroxylongifolaldehyde (4), the missing key-compound in the earlier proposed mechanism for the abnormal perbenzoic acid oxidation of longifolene is described. Rearrangement of hydroxyaldehyde (4) to hydroxyketone (6) during exposure to LAH is reported

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Studies in sesquiterpenes-L: 3-hydroxylongifolaldehyde, the elusive intermediate in the abnormal perbenzoic acid oxidation of longifolene

Abstract

Extracted data

Studies in sesquiterpenes-L: 3-hydroxylongifolaldehyde, the elusive intermediate in the abnormal perbenzoic acid oxidation of longifolene

Abstract

Extracted data

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