The development of effective coating systems that offer high protection against erosion–corrosion is of utmost importance in several industrial sectors. Such a coating class is typically designed to provide an effective barrier against aggressive environments combined with cathodic protection. The adherence to the substrate ensures full performance and reliability of the coatings during service. In the present investigation, the scratch response of single- and multi-layered composite coatings made from superimposed layers of a modified phenyl–methyl silicone resin and of aluminum–magnesium (Al–Mg 4.5 wt%) metallic powders was investigated. The applied loads, the contact conditions between the indenter and coating surface and the sliding spe...