Let R be an integral domain, h non-zero in R such that R/hR is a field, and HA the category of torsionless (or flat) Hopf algebras over R. We call any H in HA "quantized function algebra" (=QFA), resp. "quantized (restricted) universal enveloping algebra" (=QrUEA), at h if H/hH is the function algebra of a connected Poisson group, resp. the (restricted, if R/hR has positive characteristic) universal enveloping algebra of a (restricted) Lie bialgebra. We establish an "inner" Galois' correspondence on HA, via the definition of two endofunctors, ( )^\vee and ( )', of HA such that: (a) the image of ( )^\vee, resp. of ( )', is the full subcategory of all QrUEAs, resp. all QFAs, at h; (b) if R/hR has zero characteristic, the restriction of ( )^...