Alkynophilic cationic gold(I) complexes are very active catalysts for reactions of enynes that proceed exclusively through cyclopropyl carbene complexes as intermediates (see scheme). With such catalysts, the first examples of endocyclic skeletal rearrangements under mild conditions have been observed
Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rear...
Electrophilic transition-metal complexes catalyze the reaction of enynes in the presence of water or...
Gold salts and complexes are the most active catalysts for the activation of alkynes, allenes and al...
Cycloisomerizations of enynes are probably the most representative carbon-carbon bond forming reacti...
Gold(I) complexes are the most active catalysts for the biscyclopropanation of dienynes to form tetr...
Cycloisomerizations of 1,n-enynes catalyzed by gold(I) proceed via electrophilic species with a high...
The gold(I)-catalyzed cycloisomerization 1,5-enynes and 1,4-allylallenes to tetracyclododecane and t...
The cyclization of o-(alkynyl)-3-(methylbut-2-enyl)benzenes, 1,6-enynes having a condensed aromatic ...
Recently, gold-carbenoid species have been proposed as inter-mediates in gold-catalyzed enyne rearra...
The formation of saturated carbon-carbon bonds in a precise andcontrolled manner is arguably the pri...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold(I) acetylide and σ,π-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and f...
The use of N-heterocyclic carbene (NHC) as a ligand in the gold(I)-catalyzed cycloisomerization of e...
The cyclisation of 1,5-enynes containing alkenes, arenes, heteroarenes, and hydroxyl groups to form ...
Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rear...
Electrophilic transition-metal complexes catalyze the reaction of enynes in the presence of water or...
Gold salts and complexes are the most active catalysts for the activation of alkynes, allenes and al...
Cycloisomerizations of enynes are probably the most representative carbon-carbon bond forming reacti...
Gold(I) complexes are the most active catalysts for the biscyclopropanation of dienynes to form tetr...
Cycloisomerizations of 1,n-enynes catalyzed by gold(I) proceed via electrophilic species with a high...
The gold(I)-catalyzed cycloisomerization 1,5-enynes and 1,4-allylallenes to tetracyclododecane and t...
The cyclization of o-(alkynyl)-3-(methylbut-2-enyl)benzenes, 1,6-enynes having a condensed aromatic ...
Recently, gold-carbenoid species have been proposed as inter-mediates in gold-catalyzed enyne rearra...
The formation of saturated carbon-carbon bonds in a precise andcontrolled manner is arguably the pri...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold(I) acetylide and σ,π-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and f...
The use of N-heterocyclic carbene (NHC) as a ligand in the gold(I)-catalyzed cycloisomerization of e...
The cyclisation of 1,5-enynes containing alkenes, arenes, heteroarenes, and hydroxyl groups to form ...
Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rear...
Electrophilic transition-metal complexes catalyze the reaction of enynes in the presence of water or...
Gold salts and complexes are the most active catalysts for the activation of alkynes, allenes and al...