Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold
- Nieto-Oberhuber, Cristina
- López, Salomé
- Munoz-Herranz, Maria
- Cárdenas, Diego J.
- Buñuel, Elena
- Nevado, Cristina
- Echavarren, Antonio M.
Publication date
January 2005
DOI Publisher
Wiley ISSN
1433-7851 Citation count (estimate)
184Abstract
Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbene
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