Add to ORKGA slight excess of silyl trifluoromethanesulfonate mediates a tandem enol silane formation-Mukaiyama aldol reaction in the presence of Hunig’s base. Preformation of the enol silane is unnecessary for efficient reactions, which proceed in 75–97% yield for the addition of aryl methyl ketones and acetate esters to non-enolizable aldehydes. Mechanistic data suggests that free amine is crucial for full conversion
Ketones readily undergo conversion to enol silanes in the presence of trialkylamine base and trimeth...
One-pot reactions were studied in order to develop procedures for the formation of important carbon-...
para-Methoxybenzyl methyl ether acts as an alkylating agent for thiols in the presence of trimethyls...
Various ketones, esters, amides, and thioesters add in high yield to dimethyl acetals in the presenc...
Abstract: A new aldol-type reaction has been developed that does not require the extremely basic con...
Aryl alkyl ketones, acetate esters, and acetamides undergo facile one-pot enol silane formation, Muk...
In the presence of TMSOTf and a trialkylamine base, acetic acid undergoes aldol addition to non-enol...
In the presence of TMSOTf and a trialkylamine base, acetic acid undergoes aldol addition to non-enol...
Ketones, amides, and thioesters form enol silanes and add to N-phenylnitrones in one pot in the pres...
The Mukaiyama aldol reaction is a widely applied carbon–carbon bond forming reaction. However, despi...
Touched for the very first time! It is herein highlighted how acetaldehyde silyl enol ethers undergo...
The addition of aryl thioesters to imines proceeds efficiently in the presence of an amine base and ...
The chemical synthesis of organic molecules involves, at its very essence, the creation of carbon–ca...
In the presence of trimethylsilyl trifluoromethanesulfonate and trialkylamine base, thioesters are r...
Reactions that form a product with the same reactive functionality as that of one of the starting co...
Ketones readily undergo conversion to enol silanes in the presence of trialkylamine base and trimeth...
One-pot reactions were studied in order to develop procedures for the formation of important carbon-...
para-Methoxybenzyl methyl ether acts as an alkylating agent for thiols in the presence of trimethyls...
Various ketones, esters, amides, and thioesters add in high yield to dimethyl acetals in the presenc...
Abstract: A new aldol-type reaction has been developed that does not require the extremely basic con...
Aryl alkyl ketones, acetate esters, and acetamides undergo facile one-pot enol silane formation, Muk...
In the presence of TMSOTf and a trialkylamine base, acetic acid undergoes aldol addition to non-enol...
In the presence of TMSOTf and a trialkylamine base, acetic acid undergoes aldol addition to non-enol...
Ketones, amides, and thioesters form enol silanes and add to N-phenylnitrones in one pot in the pres...
The Mukaiyama aldol reaction is a widely applied carbon–carbon bond forming reaction. However, despi...
Touched for the very first time! It is herein highlighted how acetaldehyde silyl enol ethers undergo...
The addition of aryl thioesters to imines proceeds efficiently in the presence of an amine base and ...
The chemical synthesis of organic molecules involves, at its very essence, the creation of carbon–ca...
In the presence of trimethylsilyl trifluoromethanesulfonate and trialkylamine base, thioesters are r...
Reactions that form a product with the same reactive functionality as that of one of the starting co...
Ketones readily undergo conversion to enol silanes in the presence of trialkylamine base and trimeth...
One-pot reactions were studied in order to develop procedures for the formation of important carbon-...
para-Methoxybenzyl methyl ether acts as an alkylating agent for thiols in the presence of trimethyls...