Context. The nature and origin of the soft X-ray excess in radio-quiet AGN is still an open issue. The interpretation in terms of thermal disc emission has been challanged by the discovery of the constancy of the effective temperature despite the wide range of Black Hole masses of the observed sources. Alternative models are reflection from ionized matter and absorption in a relativistically smeared wind. Aims. We analyzed XMM-Newton observations of four luminous radio-quiet AGN with the aim of characterising their main properties and in particular the soft excess. Methods. Different spectral models for the soft excess were tried: thermal disc emission, Comptonization, ionized reflection, relativistically smeared winds. Results. Comptonizat...