Add to ORKGThe asymmetric Michael addition reactions using chiral imines, under neutral conditions (deracemizing alkylation process), constitute one of the main methods for the stereocontrolled elaboration of quaternary carbon centers. This protocol is based on the conjugate addition of secondary chiral enamines to electron-deficient alkenes. The focus of this report deals with the discussion of regio- and stereochemical aspects of the deracemizing alkylation process concerning enamines bearing a resident chiral center
A significant limitation of modern asymmetric catalysis is that, when applied to processes that gene...
The strategy of using chiral metal enolate intermediates in a diverse variety of asymmetric transfor...
The development of catalytic, enantioselective methods for the construction of quaternary stereogeni...
The asymmetric Michael addition reactions using chiral imines, under neutral conditions (deracemizin...
The asymmetric Michael addition reactions using chiral imines, under neutral conditions (deracemizin...
Der Aufbau quartärer Stereozentren gelingt mittels eines neuen Valinamid-Auxiliars in asymmetrischen...
N-Methylation of ligands containing a trans-1,2-diaminocyclohexane core and multiple stereogenic cen...
We present a general model for understanding the stereochemical course of intramolecular Michael rea...
The synthesis of a range of novel enantiomerically pure vicinal 1,2-diamines is described as has the...
Enantioselective propionate alkylation, as a method to control acyclic methyl~bearing stereocenters,...
The use of nonmetal based asymmetric catalysis has witnessed an extremely rapid advancement since 20...
This thesis is concerned with investigations into applications of double asymmetric induction and pa...
Over the last decade the potential of organocatalysis has successfully been demonstrated. In particu...
In this paper the addition of organolithium reagents to chiral imidoylphenols to prepare enantiopure...
A summary of the work on asymmetric reduction of carbonyl compounds with chiral alkoxyaluminium and ...
A significant limitation of modern asymmetric catalysis is that, when applied to processes that gene...
The strategy of using chiral metal enolate intermediates in a diverse variety of asymmetric transfor...
The development of catalytic, enantioselective methods for the construction of quaternary stereogeni...
The asymmetric Michael addition reactions using chiral imines, under neutral conditions (deracemizin...
The asymmetric Michael addition reactions using chiral imines, under neutral conditions (deracemizin...
Der Aufbau quartärer Stereozentren gelingt mittels eines neuen Valinamid-Auxiliars in asymmetrischen...
N-Methylation of ligands containing a trans-1,2-diaminocyclohexane core and multiple stereogenic cen...
We present a general model for understanding the stereochemical course of intramolecular Michael rea...
The synthesis of a range of novel enantiomerically pure vicinal 1,2-diamines is described as has the...
Enantioselective propionate alkylation, as a method to control acyclic methyl~bearing stereocenters,...
The use of nonmetal based asymmetric catalysis has witnessed an extremely rapid advancement since 20...
This thesis is concerned with investigations into applications of double asymmetric induction and pa...
Over the last decade the potential of organocatalysis has successfully been demonstrated. In particu...
In this paper the addition of organolithium reagents to chiral imidoylphenols to prepare enantiopure...
A summary of the work on asymmetric reduction of carbonyl compounds with chiral alkoxyaluminium and ...
A significant limitation of modern asymmetric catalysis is that, when applied to processes that gene...
The strategy of using chiral metal enolate intermediates in a diverse variety of asymmetric transfor...
The development of catalytic, enantioselective methods for the construction of quaternary stereogeni...