Novel bonding modes in metallo–dithiadiazolyl complexes: preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh<sub>3</sub>)<sub>2</sub>]·MeCN and [Pt<sub>3</sub>(µ-SNCPhNS-S,S)<sub>2</sub>(PPh<sub>3</sub>)<sub>4</sub>·2PhMe
- Banister, A.
- Gorell, I.
- Lawrence, S.
- Lehmann, C.
- May, I.
- Tate, G.
- Blake, A.
- Rawson, J.
DOIAbstract
Reaction of [Pt(PPh3)3] with (Ph[graphic omitted])2 in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh3)2]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt3(µ-SNCPhNS-S,S)2(PPh3)4]; the structures of both compounds are reported
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