International audienceArslantepe is a höyük (= tell) located within the fertile Malatya Plain, near the right bank of the Euphrates River. The site is excavated since more than 55 years by the Italian Sapienza University archaeologists and reveals periods from at least the sixth millennium BCE until the final destruction of the Neo-Hittite town. This long sequence records the changing relations and connections with various civilizations and regions of the Near East. Using the chemical characterization of a large group of artefacts (388 analysed), we propose, in this paper, a new sourcing of the obsidian used by the inhabitants of Arslantepe from the beginning of the Late Chalcolithic to the end of the Early Bronze Age. The method is based o...