Experimental

R factor = 0.037; wR factor = 0.088; data-to-parameter ratio = 14.0. In the title compound, C10H12N2OS, the toluene and the N-carbamothioylacetamide units are oriented at dihedral angle of 78.75 (5). An intramolecular N—H O hydrogen bond generates an S(6) ring. In the crystal, molecules are linked into [101] chains by pairs of N—H S hydrogen bonds [which generate R2 2(8) loops] and pairs of O—H O hydrogen bonds [which generate R2 2(4) loops]. The two motifs alternate in the chain. Related literature For related structures, see: Shahwar et al. (2012). For graph–se