Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions
- Mauro, Matteo
- Aliprandi, Alessandro
- Cebrian, Cristina
- Wang, Di
- Kuebel, Christian
- De Cola, Luisa
View in ORKG Publication date
January 2014
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1359-7345Abstract
International audienceThe solvent-assisted self-assembly of a blue-emitting neutral platinum(II) complex into micrometer-long and highly crystalline fibers has been achieved. The aggregates show highly efficient (quantum yield up to 74%) polarized yellow-orange light emission, as a consequence of their high degree of supramolecular order imparted by weak non-covalent intermolecular (metal...metal and pi-pi) interactions