International audienceA series of original heteroleptic dirhodium(II) complexes (4a-j) of formula Rh2(OAc)3(L), where L is a redox-active ferrocenecarboxylate ligand, has been prepared. These dirhodium(II) complexes have been characterised by NMR, mass spectrometry and cyclic voltammetry. All complexes show a quasi-reversible redox behaviour for the ferrocenyl unit. The latter can be selectively oxidised by [N(4-C6H4Br)3]+.BF4-. Four selected heteroleptic complexes 4a, 4b, 4f and 4i, have been evaluated as catalysts for the intramolecular decomposition of a diazo compound. The ratio between the aromatic substitution product 6 and the aliphatic C-H insertion product 7 increases (up to 19% increase) when using the in situ generated oxidised f...
An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-het...
The axial coordination of N-heterocyclic carbene ligands onto dirhodium(II) complexes was examined, ...
Dirhodium complexes are used for a broad scope of applications due, in part, to the presence of a st...
International audienceA series of original heteroleptic dirhodium(II) complexes (4a-j) of formula Rh...
WOS: 0001845765000131-Ferrocenylmethyl-3-benzylimidazolidinium iodide and 1-ferrocenylmethyl-3-( 2,4...
International audienceThe chemical oxidation of rhodium(i) complexes [Rh(L)(COD)][BF4], where L is a...
International audienceA rhodium(I) dicarbonyl complex bearing a bidentate ferrocenyl phosphine-NHC l...
Im ersten Teil dieser Arbeit wurden neue hetero- und homoleptische dimere Rhodium(II)-Benzoat-Komple...
New examples of the rare class of rhodium(I) ferrocenyl Fischer carbene complexes 1–8, [Rh(LL)Cl{C(X...
Jones'n for electrons : Various Rh complexes (see general structure) were formed with diaminoca...
This thesis is concerned with the examination of the broadly applied and highly effective dirhodium ...
The binuclear [eta(5)-(1-ferrocenyl)indenyl]Rh(NBD) (1), [eta(5)-(1-ferrocenyl)indenyl]Rh(COD) (1a),...
A series of heterobimetallic complexes of general structure [RhL2-{eta(5)-(2-ferrocenyl)indenyl}] (L...
Diamidobenzene ligands are a prominent class of redox-active ligands owing to their electron reservo...
New examples of the rare class of rhodium(I) ferrocenyl Fischer carbene complexes <b>1</b>–<b>8</b>...
An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-het...
The axial coordination of N-heterocyclic carbene ligands onto dirhodium(II) complexes was examined, ...
Dirhodium complexes are used for a broad scope of applications due, in part, to the presence of a st...
International audienceA series of original heteroleptic dirhodium(II) complexes (4a-j) of formula Rh...
WOS: 0001845765000131-Ferrocenylmethyl-3-benzylimidazolidinium iodide and 1-ferrocenylmethyl-3-( 2,4...
International audienceThe chemical oxidation of rhodium(i) complexes [Rh(L)(COD)][BF4], where L is a...
International audienceA rhodium(I) dicarbonyl complex bearing a bidentate ferrocenyl phosphine-NHC l...
Im ersten Teil dieser Arbeit wurden neue hetero- und homoleptische dimere Rhodium(II)-Benzoat-Komple...
New examples of the rare class of rhodium(I) ferrocenyl Fischer carbene complexes 1–8, [Rh(LL)Cl{C(X...
Jones'n for electrons : Various Rh complexes (see general structure) were formed with diaminoca...
This thesis is concerned with the examination of the broadly applied and highly effective dirhodium ...
The binuclear [eta(5)-(1-ferrocenyl)indenyl]Rh(NBD) (1), [eta(5)-(1-ferrocenyl)indenyl]Rh(COD) (1a),...
A series of heterobimetallic complexes of general structure [RhL2-{eta(5)-(2-ferrocenyl)indenyl}] (L...
Diamidobenzene ligands are a prominent class of redox-active ligands owing to their electron reservo...
New examples of the rare class of rhodium(I) ferrocenyl Fischer carbene complexes <b>1</b>–<b>8</b>...
An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-het...
The axial coordination of N-heterocyclic carbene ligands onto dirhodium(II) complexes was examined, ...
Dirhodium complexes are used for a broad scope of applications due, in part, to the presence of a st...