Efficient CO2 conversion by formate dehydrogenase is limited by the low CO2 concentrations that can be reached in traditional buffers. The use of ionic liquids was proposed as a manner to increase CO2 concentration in the reaction system. It has been found, however, that the required cofactor (NADH) heavily degraded during the enzymatic reaction and that acidity was the main reason. Acidity, indeed, resulted in reduction of the conversion of CO2 into formic acid and contributed to overestimate the amount of formic acid produced when the progression of the reaction was followed by a decrease in NADH absorbance (method N). Stability of NADH and the mechanism of NADH degradation was investigated by UV, NMR and by DFT calculations. It was found...
This work has developed a series of strategies for the efficient hydrogenation of CO2 to different p...
The development of simple, cost-effective and sustainable methods to transform CO2 into feedstock ch...
International audienceThe formate dehydrogenase (FDH) from Candida boidinii is a well-known enzyme i...
Efficient CO2 conversion by formate dehydrogenase is limited by the low CO2 concentrations that can ...
Low yields commonly obtained during enzymatic conversion of CO2 to methanol are attributed to low CO...
The efficient bioactivation of CO2 provides an alternative new strategy for producing high value che...
CO2 capture at the production site represents one of the accessible ways to reduce its emission in ...
This paper focuses specifically on certain ionic liquids that are capable of acting as chemisorbents...
The fixation and conversion of carbon dioxide is a controversial topic. Physical fixation or separat...
A new type of "task specific ionic liquid", tetrabutylphosphonium amino acid [P(C-4)(4)][A...
The emission of CO2 from fossil fuels is the object of an increasing worldwide attention, and althou...
Ionic liquids (ILs), a kind of novel green media composed entirely of cations and anions, have recen...
International audienceWe report electrolyte engineering strategy for CO 2 reduction into formate wit...
A new low-energy pathway is reported for the electrochemical reduction of CO2 to formate and syngas ...
The efficient transformation of CO2 into chemicals and fuels is a key challenge for the decarbonisat...
This work has developed a series of strategies for the efficient hydrogenation of CO2 to different p...
The development of simple, cost-effective and sustainable methods to transform CO2 into feedstock ch...
International audienceThe formate dehydrogenase (FDH) from Candida boidinii is a well-known enzyme i...
Efficient CO2 conversion by formate dehydrogenase is limited by the low CO2 concentrations that can ...
Low yields commonly obtained during enzymatic conversion of CO2 to methanol are attributed to low CO...
The efficient bioactivation of CO2 provides an alternative new strategy for producing high value che...
CO2 capture at the production site represents one of the accessible ways to reduce its emission in ...
This paper focuses specifically on certain ionic liquids that are capable of acting as chemisorbents...
The fixation and conversion of carbon dioxide is a controversial topic. Physical fixation or separat...
A new type of "task specific ionic liquid", tetrabutylphosphonium amino acid [P(C-4)(4)][A...
The emission of CO2 from fossil fuels is the object of an increasing worldwide attention, and althou...
Ionic liquids (ILs), a kind of novel green media composed entirely of cations and anions, have recen...
International audienceWe report electrolyte engineering strategy for CO 2 reduction into formate wit...
A new low-energy pathway is reported for the electrochemical reduction of CO2 to formate and syngas ...
The efficient transformation of CO2 into chemicals and fuels is a key challenge for the decarbonisat...
This work has developed a series of strategies for the efficient hydrogenation of CO2 to different p...
The development of simple, cost-effective and sustainable methods to transform CO2 into feedstock ch...
International audienceThe formate dehydrogenase (FDH) from Candida boidinii is a well-known enzyme i...