Picosecond Time-resolved Photoelectron Spectroscopy as a Means of Elucidating Mechanisms of Intramolecular Vibrational Energy Redistribution in Electronically Excited States of Small Aromatic Molecules

Preliminary findings are reported following the detailed analysis of intramolecular vibrational energy redistribution (IVR) in S1 para-fluorotoluene following the excitation of one quantum in the CF stretching mode ν7. It is shown that the method propos