The bimetallic µ-oxo-alkoxides are highly active for lactone ring-opening polymerization. These compounds are aggregated in solution and their mean degree of association depends on the nature of alkoxide groups, metals, and solvent; it is modified by addition of suitable ligands or temperature variations. The course of the lactone polymerization is strongly related to the structural features of the catalyst. The determination of the mean number of growing chains per catalyst molecule, the study of the polymerization kinetics, and the knowledge of the catalyst behavior during the monomer conversion have contributed to an understanding of the polymerization mechanism
This chapter describes the use of complexes of the alkaline-earth metals (magnesium, calcium, stront...
The impact of the metal size and Lewis acidity on the polymerization activity of group 13 metal comp...
Alkyl aluminium alkoxides have been used as initiators for the ring opening polymerisation of ε-capr...
peer reviewedThe bimetallic µ-oxo-alkoxides are highly active for lactone ring-opening polymerizatio...
peer reviewedThe fast and living ring-opening polymerization of lactones by bimetallic mu -oxoalkoxi...
A kinetic analysis on the aluminum salen-catalyzed ring-opening polymerization (ROP) of (macro)lacto...
A kinetic analysis on the aluminum salen-catalyzed ring-opening polymerization (ROP) of (macro)lacto...
peer reviewedThe influence of methyl substituent on the mechanism of the ring-opening polymerization...
To obtain more insight in the ring-opening polymerization of lactones, complex formation of the init...
: The ring-opening polymerisation of lactones, by different initiator-catalyst systems, has been stu...
The mechanism for the ring-opening polymerization of lactide and ε-caprolactone is presented here wi...
The mechanism of ring-opening polymerization of some lactones and lactide initiated by lanthanum iso...
peer reviewedStructure and coordinative association of the propagating species have been studied by ...
peer reviewedThe synthesis of aliphatic polyesters by the ring-opening polymerization of cyclic mono...
The kinetics of polymerization of ε-caprolactone (CL) initiated by aluminum-alkoxide complexes suppo...
This chapter describes the use of complexes of the alkaline-earth metals (magnesium, calcium, stront...
The impact of the metal size and Lewis acidity on the polymerization activity of group 13 metal comp...
Alkyl aluminium alkoxides have been used as initiators for the ring opening polymerisation of ε-capr...
peer reviewedThe bimetallic µ-oxo-alkoxides are highly active for lactone ring-opening polymerizatio...
peer reviewedThe fast and living ring-opening polymerization of lactones by bimetallic mu -oxoalkoxi...
A kinetic analysis on the aluminum salen-catalyzed ring-opening polymerization (ROP) of (macro)lacto...
A kinetic analysis on the aluminum salen-catalyzed ring-opening polymerization (ROP) of (macro)lacto...
peer reviewedThe influence of methyl substituent on the mechanism of the ring-opening polymerization...
To obtain more insight in the ring-opening polymerization of lactones, complex formation of the init...
: The ring-opening polymerisation of lactones, by different initiator-catalyst systems, has been stu...
The mechanism for the ring-opening polymerization of lactide and ε-caprolactone is presented here wi...
The mechanism of ring-opening polymerization of some lactones and lactide initiated by lanthanum iso...
peer reviewedStructure and coordinative association of the propagating species have been studied by ...
peer reviewedThe synthesis of aliphatic polyesters by the ring-opening polymerization of cyclic mono...
The kinetics of polymerization of ε-caprolactone (CL) initiated by aluminum-alkoxide complexes suppo...
This chapter describes the use of complexes of the alkaline-earth metals (magnesium, calcium, stront...
The impact of the metal size and Lewis acidity on the polymerization activity of group 13 metal comp...
Alkyl aluminium alkoxides have been used as initiators for the ring opening polymerisation of ε-capr...