R factor = 0.045; wR factor = 0.155; data-to-parameter ratio = 24.7. In the title compound, C13H10ClN3O2, the dihedral angle between the two benzene rings is 3.61 (6). In the crystal structure, molecules are linked by weak intermolecular C— H O hydrogen bonds, forming layers parallel to the bc plane. Short intermolecular Cl Cl contacts [3.491 (1) Å] are also observed. Related literature For the applications of Schiff base compounds see: Dao et al. (2000); Akbar Mobinikhaledi et al. (2009); So et al. (2007); Teoh et al. (1997). For the stability of the temperature controller used in the data collection, see: Cosier & Glaze