Development of ductile, amorphous metallic film at ambient conditions

abstract: The overall goal of this project is to use metallic nanoparticles to develop a thin, ductile amorphous film at room temperature. Currently bulk metallic glasses are mainly formed via quenching, which requires very high cooling rates to achieve an amorphous molecular structure. These formations often fail in a brittle manner. The advantages of using a bottom-up approach with amorphous nanoparticles at ambient conditions is that the ductility of the metal can be improved, and the process will be less energy intensive. The nanoparticles used are iron precursors with ATMP and DTPMP ligand stabilizers and dispersed in methanol. Three forms of experimentation were applied over the course of this project. The first was a simple, preliminary data collection approach where the particles were dispersed onto a glass slide and left to dry under various conditions. The second method was hypersonic particle deposition, which accelerated the particles to high speeds and bombarded onto a glass or silicon substrate. The third method used Langmuir-Blodgett concepts and equipment to make a film. Qualitative analyses were used to determine the efficacy of each approach, including SEM imaging. In the end, none of the approaches proved successful. The first approach showed inconsistencies in the film formation and aggregation of the particles. The results from the hypersonic particle deposition technique showed that not enough particles were deposited to make a consistent film, and many of the particles that were able to be deposited were aggregated. The Langmuir-Blodgett method showed potential, but aggregation of the particles and uneven film formation were challenges here as well. Although there are ways the three discussed experimental approaches could be optimized, the next best step is to try completely new approaches, such as convective assembly and 3D printing to form the ideal nanoparticle film