Our group has previously reported the asymmetric [2,3]-sigmatropic rearrangement of allylic ammonium ylids and its application towards the synthesis of aminoacids such as allylglycine. We now wish to report an efficient synthesis of phenylalanine derivatives via the asymmetric [1,2]-sigmatropic rearrangement of benzylic ammonium ylids. Asymmetry was introduced by using a range of chiral auxiliaries: their effect on the reaction yield and diastereoselectivity will be discussed
A new strategy has been established for the [2,3]-sigmatropic rearrangement of quaternary allylic am...
This thesis reports the development of a novel asymmetric route towards a variety of NBoc protected ...
The first investigation on catalytic asymmetric [2,3]-sigmatropic rearrangement of sulfur ylides gen...
The thesis describes the realization of an asymmetric [2,3]-sigmatropic rearrangement of achiral all...
The first examples of highly enantioselective [2,3]-sigmatropic rearrangements of acyclic allylic am...
The first examples of highly enantioselective [2,3]-sigmatropic rearrangements of acyclic allylic am...
Benzotetramisole promotes the catalytic asymmetric [2,,3]-rearrangement of allylic quaternary ammoni...
Benzotetramisole promotes the catalytic asymmetric [2,,3]-rearrangement of allylic quaternary ammoni...
[2,3]-Sigmatropic rearrangements of allylic ammonium ylids derived from glycinoylcamphorsultams are ...
[2,3]-Sigmatropic rearrangements of allylic ammonium ylids derived from glycinoylcamphorsultams are ...
[2,3]-Sigmatropic rearrangements of allylic ammonium ylids derived from glycinoylcamphorsultams are ...
Benzotetramisole promotes the catalytic asymmetric [2,3]-rearrangement of allylic quaternary ammoniu...
Highly efficient catalytic asymmetric [2,3]-sigmatropic rearrangements of propargyl ammonium salts h...
The isothiourea-catalysed chemo- and enantioselective [2,3]-sigmatropic rearrangement of N,N-diallyl...
This thesis details the development of tandem allylic amination and [2,3]-rearrangement methodologie...
A new strategy has been established for the [2,3]-sigmatropic rearrangement of quaternary allylic am...
This thesis reports the development of a novel asymmetric route towards a variety of NBoc protected ...
The first investigation on catalytic asymmetric [2,3]-sigmatropic rearrangement of sulfur ylides gen...
The thesis describes the realization of an asymmetric [2,3]-sigmatropic rearrangement of achiral all...
The first examples of highly enantioselective [2,3]-sigmatropic rearrangements of acyclic allylic am...
The first examples of highly enantioselective [2,3]-sigmatropic rearrangements of acyclic allylic am...
Benzotetramisole promotes the catalytic asymmetric [2,,3]-rearrangement of allylic quaternary ammoni...
Benzotetramisole promotes the catalytic asymmetric [2,,3]-rearrangement of allylic quaternary ammoni...
[2,3]-Sigmatropic rearrangements of allylic ammonium ylids derived from glycinoylcamphorsultams are ...
[2,3]-Sigmatropic rearrangements of allylic ammonium ylids derived from glycinoylcamphorsultams are ...
[2,3]-Sigmatropic rearrangements of allylic ammonium ylids derived from glycinoylcamphorsultams are ...
Benzotetramisole promotes the catalytic asymmetric [2,3]-rearrangement of allylic quaternary ammoniu...
Highly efficient catalytic asymmetric [2,3]-sigmatropic rearrangements of propargyl ammonium salts h...
The isothiourea-catalysed chemo- and enantioselective [2,3]-sigmatropic rearrangement of N,N-diallyl...
This thesis details the development of tandem allylic amination and [2,3]-rearrangement methodologie...
A new strategy has been established for the [2,3]-sigmatropic rearrangement of quaternary allylic am...
This thesis reports the development of a novel asymmetric route towards a variety of NBoc protected ...
The first investigation on catalytic asymmetric [2,3]-sigmatropic rearrangement of sulfur ylides gen...