An EIS study of the conservation treatment of the bronze sphinxes at the Museo Arqueológico Nacional (Madrid)

In any conservation project, conservators have to address several questions to design the appropriate intervention strategy. Among them, the effectiveness and duration of protective treatments is an important issue, not easy to evaluate. In the field of metallic cultural heritage, electrochemical techniques such as electrochemical impedance spectroscopy (EIS) can be used to evaluate patinas and protective coatings performance. Widely used in industrial applications, the use of these techniques in conservation science is much more recent and limited. During the restauration process of the bronze sphinxes at the main façade of the National Archaeological Museum in Madrid, collaboration with conservators has been established to test the performance of a recently developed gel-electrolyte cell for the electrochemical evaluation of metal cultural heritage. Electrochemical measurements (EIS and Rp) of the patinas have been carried out before, during and after the conservation treatments, on two different areas of the sculpture. This has provided information on how the protective coatings have improved corrosion resistance by 3 orders of magnitude, and how this protection is starting to decrease with time; periodic measurements will allow verifying the performance of the treatment over time and detecting the failure of the protection treatment before its effects are visible on the surface.This research has been funded by the Spanish Ministry of Economy (MINECO) with the research projects HAR2011-22402 and HAR2014-54893-R and FPI Grants BES-2012-052716 and BES-2015-071472; and by Comunidad de Madrid and European Social Fund under Geomateriales 2 Programme (S2013/MIT_2914).Peer Reviewe