Reacting white phosphorus (P4) with sterically encumbered aryl lithium reagents (aryl=2,6-dimesitylphenyl or 2,4,6-tBu3C6H2) and B(C6F5)3 gives the unique, isolable Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutane anion. Subsequent alkylation of the nucleophilic site of the RP4 anion gives access to non-symmetrical disubstituted bicyclic tetraphosphorus compounds. This novel method enables PC bond formation in a controlled fashion using white phosphorus as starting material
The functionalization of the polypnictogen ligand complexes [Cp′′2Zr(η1:1-E4)] (E=P (1 a), As (1 b);...
Bader J, Ignat'ev N, Hoge B. Synthesis of Functional Phosphates [P(C2F5)(3)F2X](-) from the Phosphor...
Phosphorus compounds are ubiquitous in the chemical sciences, finding applications throughout indust...
The transient bicyclo[1.1.0]tetraphosphabutane anion, generated from white phosphorus (P4 ) and Mes*...
The development of selective functionalization strategies of white phosphorus (P4) is important to a...
Two [3+1] fragmentations of the Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutanide Li[Mes*P4⋅ ...
Two [3+1] fragmentations of the Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutanide Li[Mes*P4⋅ ...
Two [3+1] fragmentations of the Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutanide Li[Mes*P4⋅ ...
Converting elemental white phosphorus directly into organophosphorus or polyphosphorus is meaningful...
The selective construction of P-C bonds directly from P-4 and nucleophiles is an ideal and step-econ...
Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track ...
Different reactions of Mes* substituted phosphanes (Mes* = 2,4,6-tri-tert-butylphenyl) led to the fo...
By employing the highly reducing aluminyl complex [K{(NON)Al}]<sub>2</sub> (NON=4,5-bis(...
Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track ...
Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic c...
The functionalization of the polypnictogen ligand complexes [Cp′′2Zr(η1:1-E4)] (E=P (1 a), As (1 b);...
Bader J, Ignat'ev N, Hoge B. Synthesis of Functional Phosphates [P(C2F5)(3)F2X](-) from the Phosphor...
Phosphorus compounds are ubiquitous in the chemical sciences, finding applications throughout indust...
The transient bicyclo[1.1.0]tetraphosphabutane anion, generated from white phosphorus (P4 ) and Mes*...
The development of selective functionalization strategies of white phosphorus (P4) is important to a...
Two [3+1] fragmentations of the Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutanide Li[Mes*P4⋅ ...
Two [3+1] fragmentations of the Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutanide Li[Mes*P4⋅ ...
Two [3+1] fragmentations of the Lewis acid stabilized bicyclo[1.1.0]tetraphosphabutanide Li[Mes*P4⋅ ...
Converting elemental white phosphorus directly into organophosphorus or polyphosphorus is meaningful...
The selective construction of P-C bonds directly from P-4 and nucleophiles is an ideal and step-econ...
Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track ...
Different reactions of Mes* substituted phosphanes (Mes* = 2,4,6-tri-tert-butylphenyl) led to the fo...
By employing the highly reducing aluminyl complex [K{(NON)Al}]<sub>2</sub> (NON=4,5-bis(...
Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track ...
Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic c...
The functionalization of the polypnictogen ligand complexes [Cp′′2Zr(η1:1-E4)] (E=P (1 a), As (1 b);...
Bader J, Ignat'ev N, Hoge B. Synthesis of Functional Phosphates [P(C2F5)(3)F2X](-) from the Phosphor...
Phosphorus compounds are ubiquitous in the chemical sciences, finding applications throughout indust...