Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands
- Moelands, M.A.H.
- Nijsse, S.
- Folkertsma, E.
- de Bruin, B.
- Lutz, M.
- Spek, A.L.
- Klein Gebbink, R.J.M.
- Organic Chemistry and Catalysis
- Sub Chem Biol & Organic Chem begr 1-6-12
- Sub Crystal and Structural Chemistry
DOIAbstract
A series of mononuclear Fe(II) triflate complexes based on the 3,3-bis(1-alkylimidazole-2-yl)propionate ester (BAIP) ligand scaffold are reported. Variation of the steric and electronic properties of the BAIP ligand, a mimic of the 2-His-1-carboxylate facial triad found in mononuclear-nonheme iron enzmyes, provided insight into its coordination flexibility and structural demands as a facial ligand. The Fe(II) complexes were investigated as catalysts in the epoxidation/dihydroxylation of olefins
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