The He(I) and He(II) Photoelectron Spectra of some η5-Cyclopentadienyl-Titanium, -Zirconium and -Hafnium Trihalide Complexes

Terpstra, Andries
Louwen, Jaap N.
Oskam, Ad
Teuben, Jan H.

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Publication date

January 1984

DOI

10.1016/s0022-328x(00)98696-0

ISSN

0022-328X

Abstract

The He(I) and He(II) photoelectron spectra are reported for (η5-C5H5)MX3 (M = Ti, Zr, Hf; X = Cl, Br) and some methylcyclopentadienyl and pentamethylcyclopentadienyl derivatives. Unambiguous assignments are made of the Cp orbitals, the halide a2 and e orbitals. Very regular trends are observed in the ionization energies upon substitution of the ring, metals and ligands

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The He(I) and He(II) Photoelectron Spectra of some η5-Cyclopentadienyl-Titanium, -Zirconium and -Hafnium Trihalide Complexes

Abstract

Extracted data

The He(I) and He(II) Photoelectron Spectra of some η5-Cyclopentadienyl-Titanium, -Zirconium and -Hafnium Trihalide Complexes

Abstract

Extracted data

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