On the Mechanism of the Reduction of Molecular Nitrogen with Aryldicyclopentadienyltitanium(III) Complexes

Weij, F.W. van der
Teuben, J.H.

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Publication date

January 1976

DOI

10.1016/s0022-328x(00)98028-8

ISSN

0022-328X

Abstract

The first step in the reduction of the dinitrogen ligand in (Cp2TiR)2N2 (R = C6H5, m-, p-CH3C6H4, C6F5, CH2C6H5) by sodium napthalene (NaC10H8) involves the removal of one Cp group per titanium atom. The resulting diimide precursor reacts with a second mole of NaC10H8 with formation of a hydrazine precursor. This compound is thermally unstable and decomposes to an ammonia precursor. A minor part of the hydrazine precursor abstracts a proton from the solvent

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On the Mechanism of the Reduction of Molecular Nitrogen with Aryldicyclopentadienyltitanium(III) Complexes

Abstract

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On the Mechanism of the Reduction of Molecular Nitrogen with Aryldicyclopentadienyltitanium(III) Complexes

Abstract

Extracted data

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