We consider the low-rank approximation over the real field of generic p x q x 2 arrays. For all possible combinations of p, q, and R, we present conjectures on the existence of a best rank-R approximation. Our conjectures are motivated by a detailed analysis of the boundary of the set of arrays with at most rank R. We link these results to the Candecomp/Parafac (CP) model for three-way component analysis. Essentially, CP tries to find a best rank-R approximation to a given three-way array. In the case of p x q x 2 arrays, we show (under some regularity condition) that if a best rank-R approximation does not exist, then any sequence of CP updates will exhibit diverging CP components, which implies that several components are highly correlate...