Add to ORKGThe X-ray diffraction analysis of titanocene-2,2'-bipyridyl complexes (C5H5)(2)Ti(bpy) (1), (C5HMe4)(2)Ti(bpy) (2) and (C5Me5)(2)Ti(bpy) (3) revealed that the bpy ligand is inclined to one of the cyclopentadienyl ligands in 1 and 2 whereas in 3 it lies in the plane bisecting the CE-Ti-CE angle of the titanocene skeleton. The triplet state ESR signal of solid 3 grows in intensity while those of 1 and 2 decrease in intensity with lowering of temperature down to 77 K. This behaviour shows that the symmetrical position of bpy ligand in 3 is associated with a ground triplet state and the asymmetrical position in 1 and 2 with a ground singlet state. The relation of the spin state of titanocene-bpy complexes to their structure as deduced by McPher...
Two independent synthetic routes to η<sup>2</sup>-imine titanocene complexes were developed. On one ...
Following the track of the useful titanocene [Ti(η5-C5H5)2Cl] reagent in organic synthesis, the rela...
Following the track of the useful titanocene [Ti(η5-C5H5)2Cl] reagent in organic synthesis, the rel...
The X-ray diffraction analysis of titanocene-2,2'-bipyridyl complexes (C5H5)(2)Ti(bpy) (1), (C5HMe4)...
The (borylcyclopentadienyl)titanium complex (Cp-B)TiCl3 (1; Cp-B = eta(5)-C5H4B(C6F5)(2)) reacts wit...
An e.s.r. study has been made of the formation of some intermediate dicyclopentadienyltitanium (III)...
The first thioalkyne derivatives of functionalised titanocene of formula [Ti(5-C5H4R)( 5-C5H4R)(SOCR...
Pyridine bound transition metal compounds are commonly utilized in the fields of catalysis and supra...
Bis(decamethyltitanocene) oxide, [(Cp*<sub>2</sub>Ti)<sub>2</sub>O] (<b>1</b>; Cp* = η<sup>5</sup>-...
The reaction of dipiperidinoacetylene (pipCCpip, pip = NC<sub>5</sub>H<sub>10</sub>, <b>1a</b>) wit...
A series of complexes of the type [Ti(′Cp)2Y] {′Cp = η5-C5H5 (Cp), η5-C5H4SiMe3 (SiCp), η5-1,3-C5H3(...
The molecular structure of the methylene-bridged titanocene dichloride, CH2(C5H4)2TiCl2, and that of...
Reduction of the 1,3-disubstituted titanocene complexes, (η<sup>5</sup>-C<sub>5</sub>H<sub>3</sub>-1...
Cytotoxicity of titanocene dihalides has been a persistent topic in scientific literature, dating ba...
The molecular structure of the methylene-bridged titanocene dichloride, CH2 (CsH 4)zTiCI2, and that ...
Two independent synthetic routes to η<sup>2</sup>-imine titanocene complexes were developed. On one ...
Following the track of the useful titanocene [Ti(η5-C5H5)2Cl] reagent in organic synthesis, the rela...
Following the track of the useful titanocene [Ti(η5-C5H5)2Cl] reagent in organic synthesis, the rel...
The X-ray diffraction analysis of titanocene-2,2'-bipyridyl complexes (C5H5)(2)Ti(bpy) (1), (C5HMe4)...
The (borylcyclopentadienyl)titanium complex (Cp-B)TiCl3 (1; Cp-B = eta(5)-C5H4B(C6F5)(2)) reacts wit...
An e.s.r. study has been made of the formation of some intermediate dicyclopentadienyltitanium (III)...
The first thioalkyne derivatives of functionalised titanocene of formula [Ti(5-C5H4R)( 5-C5H4R)(SOCR...
Pyridine bound transition metal compounds are commonly utilized in the fields of catalysis and supra...
Bis(decamethyltitanocene) oxide, [(Cp*<sub>2</sub>Ti)<sub>2</sub>O] (<b>1</b>; Cp* = η<sup>5</sup>-...
The reaction of dipiperidinoacetylene (pipCCpip, pip = NC<sub>5</sub>H<sub>10</sub>, <b>1a</b>) wit...
A series of complexes of the type [Ti(′Cp)2Y] {′Cp = η5-C5H5 (Cp), η5-C5H4SiMe3 (SiCp), η5-1,3-C5H3(...
The molecular structure of the methylene-bridged titanocene dichloride, CH2(C5H4)2TiCl2, and that of...
Reduction of the 1,3-disubstituted titanocene complexes, (η<sup>5</sup>-C<sub>5</sub>H<sub>3</sub>-1...
Cytotoxicity of titanocene dihalides has been a persistent topic in scientific literature, dating ba...
The molecular structure of the methylene-bridged titanocene dichloride, CH2 (CsH 4)zTiCI2, and that ...
Two independent synthetic routes to η<sup>2</sup>-imine titanocene complexes were developed. On one ...
Following the track of the useful titanocene [Ti(η5-C5H5)2Cl] reagent in organic synthesis, the rela...
Following the track of the useful titanocene [Ti(η5-C5H5)2Cl] reagent in organic synthesis, the rel...