The synthesis of 11 calix[4]arene‐based carceplexes obtained by solvent or doped inclusion is reported. Carceplexes with amides, for example, DMF, NMP, and 1,5‐dimethyl‐2‐pyrrolidinone, and sulfoxides, for example, DMSO and thiolane‐1‐oxide, were obtained by solvent inclusion. In these cases the yield of the carceplex decreases with increasing guest size. Potential guests that do not form carceplexes by solvent inclusion, such as 2‐butanone and 3‐sulfolene, could be incarcerated by doped inclusion with 1,5‐dimethyl‐2‐pyrrolidinone as a solvent “doped” with 5–15 vol% of potential guest. The amide bridges of the carceplexes were converted into thioamide bridges in essentially quantitative yield by means of Lawesson's reagent in refluxing xyle...
The synthesis of two new inherently chiral calix[4]arenes (ICCs, 1 and 2), endowed with electron-ric...
To gain information on CH-π aromatic interactions involved in the formation of host-guest adducts, t...
A combined computational (molecular mechanics calculations) and experimental (synthesis, NMR studies...
New calix[4]arene-based carceplexes are obtained via solvent or doped inclusion; chemical modificati...
13C CP/MAS spectroscopy of calix[4]arene-based carceplexes shows that in the solid state the cavity ...
Treatment of tetraaIcohol 1 with glutaroyl (2a, n = 3), adipoyl (2b, n = 4), and pimeloyl (2c, n = 5...
Carcerand is an organic host compound which complexes small compound(s) within its cavity and the co...
This Account reviews the synthesis, conformations, and supramolecular properties of calixarenes endo...
Treatment of tetraaIcohol 1 with glutaroyl (2a, n = 3), adipoyl (2b, n = 4), and pimeloyl (2c, n = 5...
Two glycoclusters constituted by four fully acetylated β-acetylmannosamine residues linked through t...
This article discuss about derivatization method of calix[4]arene to amide, and their conformationsT...
The main goals of the thesis work is to investigate the formation and applications of a class of hos...
The selective introduction of two and four L-alanine and L-alanyl-L-alanine groups into calix[4]aren...
Calix[4]arenes diametrically substituted at the upper rim with two melamine units spontaneously form...
New disulfide linked [4]carceplex 54»guests was synthesized. This kind of carceplex has diastereoto...
The synthesis of two new inherently chiral calix[4]arenes (ICCs, 1 and 2), endowed with electron-ric...
To gain information on CH-π aromatic interactions involved in the formation of host-guest adducts, t...
A combined computational (molecular mechanics calculations) and experimental (synthesis, NMR studies...
New calix[4]arene-based carceplexes are obtained via solvent or doped inclusion; chemical modificati...
13C CP/MAS spectroscopy of calix[4]arene-based carceplexes shows that in the solid state the cavity ...
Treatment of tetraaIcohol 1 with glutaroyl (2a, n = 3), adipoyl (2b, n = 4), and pimeloyl (2c, n = 5...
Carcerand is an organic host compound which complexes small compound(s) within its cavity and the co...
This Account reviews the synthesis, conformations, and supramolecular properties of calixarenes endo...
Treatment of tetraaIcohol 1 with glutaroyl (2a, n = 3), adipoyl (2b, n = 4), and pimeloyl (2c, n = 5...
Two glycoclusters constituted by four fully acetylated β-acetylmannosamine residues linked through t...
This article discuss about derivatization method of calix[4]arene to amide, and their conformationsT...
The main goals of the thesis work is to investigate the formation and applications of a class of hos...
The selective introduction of two and four L-alanine and L-alanyl-L-alanine groups into calix[4]aren...
Calix[4]arenes diametrically substituted at the upper rim with two melamine units spontaneously form...
New disulfide linked [4]carceplex 54»guests was synthesized. This kind of carceplex has diastereoto...
The synthesis of two new inherently chiral calix[4]arenes (ICCs, 1 and 2), endowed with electron-ric...
To gain information on CH-π aromatic interactions involved in the formation of host-guest adducts, t...
A combined computational (molecular mechanics calculations) and experimental (synthesis, NMR studies...