The free enthalpy correction parameter g in the Flory-Huggins equation for the Gibbs free enthalpy of mixing in polymer solutions is considered generally as a concentration- and temperature-independent parameter. It has been extended here with linear concentration- and temperature-dependent terms. With these parameters, six different types of cloudpoint curves can be predicted. Using the experimental cloudpoint curve for solutions of poly(2,6-dimethyl-1,4-phenylene oxide) in toluene up to about 70 per cent by weight of polymer, a set of g-parameters is obtained, accounting for concentration and temperature dependence. With the parameters thus obtained, the melting point curve has been calculated which agrees very well with the experimental ...
The cloud-point temperatures (T-c1's) of ti-ans-decahydronaphthalene (TD)/polystyrene (PS, M-w = 270...
International audienceThe cloud point curves of polyethoxylated surfactants are established experime...
The phase-separation phenomena observed in solutions of poly(2,6 dimethyl-1,4 phenylene oxide) in to...
Abstract--The free enthalpy correction parameter g in the Flory-Huggins equation for the Gibbs free ...
The free enthalpy correction parameter g in the Flory-Huggins equation for the Gibbs free enthalpy o...
In liquid systems where it is possible to perform light scattering experiments at the melting points...
Melting-point curves for solutions of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) in a series of ho...
New experimental data have been collected on thermodynamic properties of solutions of poly(2,6-dimet...
New experimental data have been collected on thermodynamic properties of solutions of poly(2,6-dimet...
In the system poly(2, 6-dimethy1-1, 4-phenylene oxide) (PPO)-toluene three phase separation lines ca...
The cloud‐point curves of polystyrene (PS) mixed with reactive epoxy monomers based on diglycidyl et...
The Edwards path-integral description of chain statistics is used to derive an effective $\phi^4$ fi...
The Edwards path-integral description of chain statistics is used to derive an effective $\phi^4$ fi...
The phase behavior of different carboxylic acids/nonionic polymer/water systems has been studied. Th...
The phase-separation phenomena observed in solutions of poly(2,6 dimethyl-1,4 phenylene oxide) in to...
The cloud-point temperatures (T-c1's) of ti-ans-decahydronaphthalene (TD)/polystyrene (PS, M-w = 270...
International audienceThe cloud point curves of polyethoxylated surfactants are established experime...
The phase-separation phenomena observed in solutions of poly(2,6 dimethyl-1,4 phenylene oxide) in to...
Abstract--The free enthalpy correction parameter g in the Flory-Huggins equation for the Gibbs free ...
The free enthalpy correction parameter g in the Flory-Huggins equation for the Gibbs free enthalpy o...
In liquid systems where it is possible to perform light scattering experiments at the melting points...
Melting-point curves for solutions of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) in a series of ho...
New experimental data have been collected on thermodynamic properties of solutions of poly(2,6-dimet...
New experimental data have been collected on thermodynamic properties of solutions of poly(2,6-dimet...
In the system poly(2, 6-dimethy1-1, 4-phenylene oxide) (PPO)-toluene three phase separation lines ca...
The cloud‐point curves of polystyrene (PS) mixed with reactive epoxy monomers based on diglycidyl et...
The Edwards path-integral description of chain statistics is used to derive an effective $\phi^4$ fi...
The Edwards path-integral description of chain statistics is used to derive an effective $\phi^4$ fi...
The phase behavior of different carboxylic acids/nonionic polymer/water systems has been studied. Th...
The phase-separation phenomena observed in solutions of poly(2,6 dimethyl-1,4 phenylene oxide) in to...
The cloud-point temperatures (T-c1's) of ti-ans-decahydronaphthalene (TD)/polystyrene (PS, M-w = 270...
International audienceThe cloud point curves of polyethoxylated surfactants are established experime...
The phase-separation phenomena observed in solutions of poly(2,6 dimethyl-1,4 phenylene oxide) in to...