The title complex, [Cu(C21H38N5Si)(C18H15P)], was obtained from the one-pot reaction between (Dipp)N(Li)SiMe3 (Dipp = 2,6-diisopropylphenyl), Me2NCN, CuCl and PPh3. The CuI atom has a distorted trigonal–planar coordination sphere. The triazapentadienyl ligand acts as a κ2-donor. The N—Cu—N bond angle is 95.88 (14)°. In the triazapentadienyl fragment, the C—N bond lengths are in the range 1.328 (5)–1.349 (5) Å, which indicates delocalization of the π-electrons in the NCNCN system
The title trinuclear compound, [Cu3(C5H8NS2)Cl2(C6H15P)3], has the dithiocarbamate ligand symmetrica...
The co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I...
The title compound, [Cu(C4H2Cl6N3)2], was obtained by the reaction of CCl3CN with ammonia in presenc...
In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphospha...
The title compound, {[Cu2I2(C12H8N6)(C18H15P)2]·2CH3CN}n, contains centrosymmetric dinuclea...
In the title complex, [CuCl(C3H4N2)(C18H15P)2], the coordination geometry around CuI is distorted te...
The asymmetric unit of the title compound, [Cu(NCS)(C3H8N2S)(C27H26P2)], contains two independent mo...
In the crystal structure of the title compound, [Cu(C₁₈H₁₆N₆)(C₃₆H₂₈OP₂)]PF₆ 0.5 CH₂Cl₂ or [Cu(DPEPh...
In the title mononuclear coordination complex, [CuFe(C5H5)(C9H5F3O2)(C18H15P)2], the CuI ion is coor...
R factor = 0.053; wR factor = 0.111; data-to-parameter ratio = 15.4. The title compound, [CuCl(C3H8N...
Dedicated to Dr John Zdysiewicz on the occasion of his retirement The X-ray crystal structure determ...
The mononuclear mixed-ligand title complex, [CuCl(C7H7N3O2S)(C18H15P)2], displays a distorted tetrah...
The coordination geometry of the Cu atom in the title compound, [CuI(C7H8N2S)(C18H15P)2], is distort...
cited By 27International audienceOver the last decades, our understanding of σ-bond activation at tr...
Through a diffusion reaction, cuprous bromide, triphenylphosphane and 1,3-bis(pyridin-4-yl)propane (...
The title trinuclear compound, [Cu3(C5H8NS2)Cl2(C6H15P)3], has the dithiocarbamate ligand symmetrica...
The co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I...
The title compound, [Cu(C4H2Cl6N3)2], was obtained by the reaction of CCl3CN with ammonia in presenc...
In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphospha...
The title compound, {[Cu2I2(C12H8N6)(C18H15P)2]·2CH3CN}n, contains centrosymmetric dinuclea...
In the title complex, [CuCl(C3H4N2)(C18H15P)2], the coordination geometry around CuI is distorted te...
The asymmetric unit of the title compound, [Cu(NCS)(C3H8N2S)(C27H26P2)], contains two independent mo...
In the crystal structure of the title compound, [Cu(C₁₈H₁₆N₆)(C₃₆H₂₈OP₂)]PF₆ 0.5 CH₂Cl₂ or [Cu(DPEPh...
In the title mononuclear coordination complex, [CuFe(C5H5)(C9H5F3O2)(C18H15P)2], the CuI ion is coor...
R factor = 0.053; wR factor = 0.111; data-to-parameter ratio = 15.4. The title compound, [CuCl(C3H8N...
Dedicated to Dr John Zdysiewicz on the occasion of his retirement The X-ray crystal structure determ...
The mononuclear mixed-ligand title complex, [CuCl(C7H7N3O2S)(C18H15P)2], displays a distorted tetrah...
The coordination geometry of the Cu atom in the title compound, [CuI(C7H8N2S)(C18H15P)2], is distort...
cited By 27International audienceOver the last decades, our understanding of σ-bond activation at tr...
Through a diffusion reaction, cuprous bromide, triphenylphosphane and 1,3-bis(pyridin-4-yl)propane (...
The title trinuclear compound, [Cu3(C5H8NS2)Cl2(C6H15P)3], has the dithiocarbamate ligand symmetrica...
The co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I...
The title compound, [Cu(C4H2Cl6N3)2], was obtained by the reaction of CCl3CN with ammonia in presenc...