Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions
Readily available difluoroenol iodides and stannanes undergo palladium-catalysed coupling reactions ...
This thesis describes the synthesis of gem-difluorinated cyclic molecules using building block appro...
A difluorodienophile, synthesised using a Stille coupling reaction underwent tin(IV)-catalysed cyclo...
Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via conci...
Direct precursors to analogues of pentopyranoses, 6-deoxyhexoses, and hexoses, in which a CF2 center...
Alkenoate 5 prepared on a multigramme scale from trifluoroethanol underwent cycloaddition with furan...
This thesis describes the synthesis of difluorinated gem-fluorinated cyclooctenone analogues using b...
Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective ox...
Trifluoroethanol has been elaborated, via a telescoped sequence involving a metalated difluoroenol, ...
A range of pentopyranosyl phosphate mimetics including 2,2-difluoro-3R*,4R*- dihydroxy-9-oxa-1S*,5R*...
α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol v...
Enantiopure 1,4-difluoro-cyclohexenes were prepared from readily available acetonide-protected (3 S,...
This thesis describes stereospecific fluorination reactions, and addresses the synthesis of fluorosu...
Metallated haloalkenes were used to open epoxides in moderate to good yield. The homoallylic alcohol...
This thesis describes the synthesis of highly substituted geminally difluorinated cyclohexenols base...
Readily available difluoroenol iodides and stannanes undergo palladium-catalysed coupling reactions ...
This thesis describes the synthesis of gem-difluorinated cyclic molecules using building block appro...
A difluorodienophile, synthesised using a Stille coupling reaction underwent tin(IV)-catalysed cyclo...
Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via conci...
Direct precursors to analogues of pentopyranoses, 6-deoxyhexoses, and hexoses, in which a CF2 center...
Alkenoate 5 prepared on a multigramme scale from trifluoroethanol underwent cycloaddition with furan...
This thesis describes the synthesis of difluorinated gem-fluorinated cyclooctenone analogues using b...
Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective ox...
Trifluoroethanol has been elaborated, via a telescoped sequence involving a metalated difluoroenol, ...
A range of pentopyranosyl phosphate mimetics including 2,2-difluoro-3R*,4R*- dihydroxy-9-oxa-1S*,5R*...
α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol v...
Enantiopure 1,4-difluoro-cyclohexenes were prepared from readily available acetonide-protected (3 S,...
This thesis describes stereospecific fluorination reactions, and addresses the synthesis of fluorosu...
Metallated haloalkenes were used to open epoxides in moderate to good yield. The homoallylic alcohol...
This thesis describes the synthesis of highly substituted geminally difluorinated cyclohexenols base...
Readily available difluoroenol iodides and stannanes undergo palladium-catalysed coupling reactions ...
This thesis describes the synthesis of gem-difluorinated cyclic molecules using building block appro...
A difluorodienophile, synthesised using a Stille coupling reaction underwent tin(IV)-catalysed cyclo...