Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site
- Orain, Pierre-Yves
- Capon, Jean-François
- Kervarec, Nelly
- Gloaguen, Frederic
- Pétillon, François Y.
- Pichon, Roger
- Schollhammer, Philippe,
- Talarmin, Jean
Publication date
July 2007
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1477-9226Abstract
International audienceTreatment of [Fe2(µ-pdt)(CO)6] (pdt = S(CH2)3S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe2(µ-pdt)(CO)4(phen)] (1); the protonation of 1 with HBF4·OEt2 in CD2Cl2 at 203 K has been monitored by 1H NMR
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