Add to ORKGA temperature-heat content relation is presented for binary systems which show solid solutions. Contrary to previous equations, the present equation accounts for the very restricted rate of diffusion in the solid. The equation is based on local equilibrium during freezing and melting. The equation obtaining to the comparative method of impurity determination and applicable to a gradually frozen sample is identical to the equation previously derived on the basis of total equilibrium. The corresponding equations of the absolute method differ considerably. Experiments confirm the local equilibrium theory and show the inadequacy of the total equilibrium theory
When attempts are made to interpret the solid-liquid transition in terms of molecular structure, hig...
We propose a conceptual model for progressive freeze concentration, which predicts solute loss throu...
The layer growth rates and resulting crystal purity during solid-layer melt crystallization were exp...
A temperature-heat content relation is presented for binary systems which show solid solutions. Cont...
The determination of the impurity content of a sample by means of the meltingcurve method (calorimet...
The methods currently used by metrologists for estimating the influence of impurities in metal fixed...
Abstract: The self-consistent model of crystallization of alloy with impurity in the c...
The possibility of growing crystals with homogeneous impurity distribution over crystal height has b...
A knowledge of the effect of impurities at the level of parts per million on the freezing temperatu...
A solution is presented to the problem of phase changes in a semi-infinite region of liquid or solid...
Calibrations of Standard Platinum Resistance Thermometers (SPRTs), the defined interpolating instrum...
We report a theory of freezing based on analysis of the solutions of the equation describing the inh...
The purpose of the present study is to present simple and effective numerical and analytical solutio...
Crystallization and melting are phase transitions of first type, which can proceed with a finite rat...
The International Temperature Scale of 1990 (ITS-90) assigns agreed temperatures to the phase transi...
When attempts are made to interpret the solid-liquid transition in terms of molecular structure, hig...
We propose a conceptual model for progressive freeze concentration, which predicts solute loss throu...
The layer growth rates and resulting crystal purity during solid-layer melt crystallization were exp...
A temperature-heat content relation is presented for binary systems which show solid solutions. Cont...
The determination of the impurity content of a sample by means of the meltingcurve method (calorimet...
The methods currently used by metrologists for estimating the influence of impurities in metal fixed...
Abstract: The self-consistent model of crystallization of alloy with impurity in the c...
The possibility of growing crystals with homogeneous impurity distribution over crystal height has b...
A knowledge of the effect of impurities at the level of parts per million on the freezing temperatu...
A solution is presented to the problem of phase changes in a semi-infinite region of liquid or solid...
Calibrations of Standard Platinum Resistance Thermometers (SPRTs), the defined interpolating instrum...
We report a theory of freezing based on analysis of the solutions of the equation describing the inh...
The purpose of the present study is to present simple and effective numerical and analytical solutio...
Crystallization and melting are phase transitions of first type, which can proceed with a finite rat...
The International Temperature Scale of 1990 (ITS-90) assigns agreed temperatures to the phase transi...
When attempts are made to interpret the solid-liquid transition in terms of molecular structure, hig...
We propose a conceptual model for progressive freeze concentration, which predicts solute loss throu...
The layer growth rates and resulting crystal purity during solid-layer melt crystallization were exp...