Add to ORKGEfficient procedures for the trimethylsilylation of the transient carbenoids H2C=CHCH(X)Li and Ph(CH(X)Li (X = Cl or Br) are described
The elucidation of a robust and reliable sequence for the generation of highly reactive transient si...
Tribromomelamine (TBM) can be used as a novel catalyst for the trimethylsilylation of alcohols and p...
Butadiene trapping experiments demonstrated that the silylenoids, :SiMeCl and :SiC12, are intermedia...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
The reaction of aryl halides with hexamethyldisilane and potassium methoxide (or sodium methoxide o...
Includes bibliographical references.Includes illustrations.The reaction of both cis- and trans-beta-...
I. Trimethylsilylpotassium reacts with epoxides to give olefins with inversion of stereochemistry. T...
A new method for consecutive α- and β-activation of propiolates toward electrophiles has been develo...
International audienceα-Alkynyl-α′-trimethylsilylhydrazones are used as novel Rh(II)-carbenoids prec...
To this date, no techniques have been determined to make physically large amounts of the products de...
3-Trimethylsilylcyclobutylidene was generated by pyrolysis of the sodium salt of the tosylhydrazone ...
A general method for generation of allyl carbenium ions from propargyl silanes via a 1,2-silyl shift...
Includes bibliographical references.Includes illustrations.A project to unequivocally characterize b...
2,2,2-Trichloromethylcarbinols are <b>1</b> are valuable synthetic intermediates with a multitude of...
The reactions of bis (trimethylsilyl) peroxide with alkyl, vinyl, alkynyl, aromatic and heteroaromat...
The elucidation of a robust and reliable sequence for the generation of highly reactive transient si...
Tribromomelamine (TBM) can be used as a novel catalyst for the trimethylsilylation of alcohols and p...
Butadiene trapping experiments demonstrated that the silylenoids, :SiMeCl and :SiC12, are intermedia...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
The reaction of aryl halides with hexamethyldisilane and potassium methoxide (or sodium methoxide o...
Includes bibliographical references.Includes illustrations.The reaction of both cis- and trans-beta-...
I. Trimethylsilylpotassium reacts with epoxides to give olefins with inversion of stereochemistry. T...
A new method for consecutive α- and β-activation of propiolates toward electrophiles has been develo...
International audienceα-Alkynyl-α′-trimethylsilylhydrazones are used as novel Rh(II)-carbenoids prec...
To this date, no techniques have been determined to make physically large amounts of the products de...
3-Trimethylsilylcyclobutylidene was generated by pyrolysis of the sodium salt of the tosylhydrazone ...
A general method for generation of allyl carbenium ions from propargyl silanes via a 1,2-silyl shift...
Includes bibliographical references.Includes illustrations.A project to unequivocally characterize b...
2,2,2-Trichloromethylcarbinols are <b>1</b> are valuable synthetic intermediates with a multitude of...
The reactions of bis (trimethylsilyl) peroxide with alkyl, vinyl, alkynyl, aromatic and heteroaromat...
The elucidation of a robust and reliable sequence for the generation of highly reactive transient si...
Tribromomelamine (TBM) can be used as a novel catalyst for the trimethylsilylation of alcohols and p...
Butadiene trapping experiments demonstrated that the silylenoids, :SiMeCl and :SiC12, are intermedia...