Add to ORKGThe site selectivity of metallation in the cyclopalladation of substituted diaminobenzenes is influenced to differing extents by the solvent, palladium precursor [Pd], reaction temperatures, reagent and organic base concentrations and substitution of groups on the aryldiamine (see below). For instance, C-Si bond cleavage is favored over C-H bond activation when a SiMe3 group is present and the reaction is carried out in a protic solvent such as MeOH
ABSTRACT: The first selective coupling of a carbon nucleophile with methyl, ethyl, propyl, and butyl...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
Pd-mediated cycloisomerization of 3-C-alkynyl-allo- and ribofuranose derivatives was investigated in...
The most attractive and fundamental interaction between metal centers and organic molecules that cou...
Cyclometalation reactions have been studied intensely for the past few decades especially those cont...
2-(1-Naphthyl)-pyridine () possesses sp(2) C-H bonds in both the γ- and δ-positions and is therefore...
The ligand-directed C—H activation relies on a coordinating donor atom being in proximity to the C—H...
Transmetalation of a 1,4-diphenyl-substituted 1,2,3-triazolylidene silver complex with an electrophi...
The reaction of dimesityl selenide (Mes(2)Se) with either PdCl2(PhCN)(2) in toluene or PdCl2 in tolu...
The reaction of dimesityl selenide (Mes2Se) with either PdCl2(PhCN) 2 in toluene or PdCl2 in toluene...
Complexes of 1-trimethyisilyl-1,5-cyclooetadiene (TMS-COD, 2) with AgI, RhI, PdII and PtII have been...
Bibliography: pages 69-72The preparation of (1-trimethylsiloxycyclopropyl)- trimethylsilane was expl...
This thesis is a summary of four papers concerning various aspects on the transition metal catalysed...
The choice of the silyl scavenger shows a substantial influence on the diastereoselectivity of the c...
Complexes of 1-trimethylsilyl-1,5-cyclooctadiene (TMS-COD) with AgI, RhI, PdII and PtII have be...
ABSTRACT: The first selective coupling of a carbon nucleophile with methyl, ethyl, propyl, and butyl...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
Pd-mediated cycloisomerization of 3-C-alkynyl-allo- and ribofuranose derivatives was investigated in...
The most attractive and fundamental interaction between metal centers and organic molecules that cou...
Cyclometalation reactions have been studied intensely for the past few decades especially those cont...
2-(1-Naphthyl)-pyridine () possesses sp(2) C-H bonds in both the γ- and δ-positions and is therefore...
The ligand-directed C—H activation relies on a coordinating donor atom being in proximity to the C—H...
Transmetalation of a 1,4-diphenyl-substituted 1,2,3-triazolylidene silver complex with an electrophi...
The reaction of dimesityl selenide (Mes(2)Se) with either PdCl2(PhCN)(2) in toluene or PdCl2 in tolu...
The reaction of dimesityl selenide (Mes2Se) with either PdCl2(PhCN) 2 in toluene or PdCl2 in toluene...
Complexes of 1-trimethyisilyl-1,5-cyclooetadiene (TMS-COD, 2) with AgI, RhI, PdII and PtII have been...
Bibliography: pages 69-72The preparation of (1-trimethylsiloxycyclopropyl)- trimethylsilane was expl...
This thesis is a summary of four papers concerning various aspects on the transition metal catalysed...
The choice of the silyl scavenger shows a substantial influence on the diastereoselectivity of the c...
Complexes of 1-trimethylsilyl-1,5-cyclooctadiene (TMS-COD) with AgI, RhI, PdII and PtII have be...
ABSTRACT: The first selective coupling of a carbon nucleophile with methyl, ethyl, propyl, and butyl...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
Pd-mediated cycloisomerization of 3-C-alkynyl-allo- and ribofuranose derivatives was investigated in...