Enhanced CO2 sorption and selectivity by functionalization of a NbO-type metal-organic framework with polarized benzothiadiazole moieties
- Song, C.
- He, Y.
- Li, B.
- Ling, Y.
- Wang, H.
- Feng, Y.
- Krishna, R.
- Chen, B.
DOIAbstract
A new NbO-type metal-organic framework ZJNU-40 incorporating highly polarized benzothiadiazole moieties exhibits a high CO2 uptake of 108 cm(3) g(-1) at 296 K and 1 atm, as well as good adsorption selectivities of CO2 over CH4 and N-2 at room temperature, which is superior to that of the analogous MOF NOTT-101
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