Open-Shell First-Row Transition-Metal Polyhydride Complexes Based on the fac-[RuH3(PR3)3]- Building Block
- Plois, M.
- Hujo, W.
- Grimme, S.
- Schwickert, C.
- Bill, E.
- de Bruin, B.
- Pöttgen, R.
- Wolf, R.
Publication date
January 2013
DOIAbstract
High-spin hydrides: A new class of stable paramagnetic polyhydride complexes [M{Ru(μ-H)3(PTol3)3}2] (M=Cr-Ni) with an unprecedented trinuclear arrangement has been synthesized. The high-spin central 3d metal ion is sandwiched between six hydride ligands in a distorted octahedral fashion
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