The preparation of shelf-stable crystalline salts of tert-butylmethylphosphinous acid borane 1 is described. X-ray analysis of diisopropylammonium tert-butylmethylphosphinite borane 4 revealed the existence of a cyclic hydrogen-bond network in the solid state which accounts for the increased melting point and stability. Dialkylammonium phosphinite boranes are convenient precursors of the chiral tert-butylmethylphosphine fragment. Compound 4 can be directly employed in SN2@P reactions with different nucleophiles to yield valuable P-stereogenic intermediates and ligands
The synthesis of new P-stereogenic ligands and investigation of their use in a Co-catalysed asymmetr...
The synthesis of P-stereogenic ligands bearing 2,6-disubstituted phenyl groups at the P atom is a ch...
Unprecedented metalated phosphonite boranes were prepared from PH-substituted precursors and silyl a...
The preparation of shelf-stable crystalline salts of tert-butylmethylphosphinous acid borane 1 is de...
The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The re...
A novel one-pot reductive methodol. for the synthesis of optically pure tert-butylmethylphosphine-bo...
(Dicyclohexylphosphino) borane is a precursor in the synthesis of water-soluble phosphines. The bora...
The synthesis of P-stereogenic bisphosphine ligands starting from a phosphinous acid chiral synthon ...
Stereochemically pure phosphines with phosphorus-heteroatom bonds and P-centered chirality are a pro...
Methylation of P-stereogenic phosphiranes Mes*PCH2CH(R) (Mes* = 2,4,6-(t-Bu)3C6H2, R = Me, Ph) with ...
International audienceThe synthesis of P-stereogenic aminophos-phine-boranes has been developed on t...
A new family of H-adamantylphosphinates as universal precursors of P-stereogenic ligands was obtaine...
Metalation of secondary diaminophosphine boranes by alkali metal amides provides a robust and select...
The development of new methods for the synthesis of organophosphorus compounds is still an important...
International audienceThis chapter is dedicated to the main achievements since 2007 regarding the sy...
The synthesis of new P-stereogenic ligands and investigation of their use in a Co-catalysed asymmetr...
The synthesis of P-stereogenic ligands bearing 2,6-disubstituted phenyl groups at the P atom is a ch...
Unprecedented metalated phosphonite boranes were prepared from PH-substituted precursors and silyl a...
The preparation of shelf-stable crystalline salts of tert-butylmethylphosphinous acid borane 1 is de...
The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The re...
A novel one-pot reductive methodol. for the synthesis of optically pure tert-butylmethylphosphine-bo...
(Dicyclohexylphosphino) borane is a precursor in the synthesis of water-soluble phosphines. The bora...
The synthesis of P-stereogenic bisphosphine ligands starting from a phosphinous acid chiral synthon ...
Stereochemically pure phosphines with phosphorus-heteroatom bonds and P-centered chirality are a pro...
Methylation of P-stereogenic phosphiranes Mes*PCH2CH(R) (Mes* = 2,4,6-(t-Bu)3C6H2, R = Me, Ph) with ...
International audienceThe synthesis of P-stereogenic aminophos-phine-boranes has been developed on t...
A new family of H-adamantylphosphinates as universal precursors of P-stereogenic ligands was obtaine...
Metalation of secondary diaminophosphine boranes by alkali metal amides provides a robust and select...
The development of new methods for the synthesis of organophosphorus compounds is still an important...
International audienceThis chapter is dedicated to the main achievements since 2007 regarding the sy...
The synthesis of new P-stereogenic ligands and investigation of their use in a Co-catalysed asymmetr...
The synthesis of P-stereogenic ligands bearing 2,6-disubstituted phenyl groups at the P atom is a ch...
Unprecedented metalated phosphonite boranes were prepared from PH-substituted precursors and silyl a...