Chemical abundances of the damped Lyman alpha systems in the XQ-100 survey

The XQ-100 survey has provided high signal-noise spectra of 100 redshift 3-4.5 quasars with the X-Shooter spectrograph. The metal abundances for 13 elements in the 41 damped Ly ¿ systems (DLAs) identified in the XQ-100 sample are presented, and an investigation into abundances of a variety of DLA classes is conducted. The XQ-100 DLA sample contains five DLAs within 5000 km s-1 of their host quasar (proximate DLAs; PDLAs) as well as three sightlines which contain two DLAs within 10 000 km s-1 of each other along the same line of sight (multiple DLAs; MDLAs). Combined with previous observations in the literature, we demonstrate that PDLAs with log N(H I) ¿ 21.0 show lower [S/H] and [Fe/H] [relative to intervening systems with similar redshift and N(H I)], whilst higher [S/H] and [Si/H] are seen in PDLAs with log N(H I) ¿ 21.0. These abundance discrepancies are independent of their line-of-sight velocity separation from the host quasar, and the velocity width of the metal lines (v90). Contrary to previous studies, MDLAs show no difference in [¿/Fe] relative to single DLAs matched in metallicity and redshift. In addition, we present follow-up UVES data of J0034+1639, a sightline containing three DLAs, including a metal-poor DLA with [Fe/H] = -2.82 (the third lowest [Fe/H] in DLAs identified to date) at zabs = 4.25. Lastly we study the dust-corrected [Zn/Fe], emphasizing that near-IR coverage of X-Shooter provides unprecedented access to Mg II, Ca II and Ti II lines (at redshifts 3-4) to provide additional evidence for subsolar [Zn/Fe] ratio in DLAs. © 2016, The Authors Published by Oxford University Press on behalf of the Royal Astronomical Society.SLE acknowledges the receipt of an NSERC Discovery Grant which supported this research. JXP is supported by NSF grant AST-1109447. SL has been supported by FONDECYT grant number 1140838 and partially by PFB-06 CATA. KDD is supported by an NSF AAPF fellowship awarded under NSF grant AST-1302093.Peer Reviewe