A self-assembled bis(pyrrolo)tetrathiafulvalene-based redox active squarew

International audienceThe synthesis and full characterization of a redox-active p-donating molecular square is described, through coordination-driven self-assembly of a new key bis(pyrrolo)TTF building block with Pt(II) salts; the electrochemical behaviour of the square is consistent with noninteracting bis(pyrrolo)TTF units