This thesis presents the preparation and catalytic reactivity of novel half-sandwich ruthenium complexes supported by N-Heterocyclic Carbene (NHC) ligands. The cationic half-sandwich ruthenium complexes [Cp(IPr)Ru(CH3CN)2]+ show interesting reactivities toward the transfer hydrogenation of different unsaturated substrates, such as ketones, olefins, N-heterocycles, and nitriles. Kinetic studies disclose that a neutral trishydride ruthenium complex is actually involved in the catalytic cycle, playing the role as a resting state. Further investigations on the sub-class of trishydride ruthenium complexes bearing NHC ligands (Cp'(NHC)RuH3) reveal that these complexes have an unusual and great catalytic performance toward the hydrodefluorination...
N-heterocyclic carbene (NHC) based ruthenium complexes were studied as catalysts for the transfer hy...
Since its discovery by Paul Sabatier, catalytic hydrogenation of unsaturated substrates has become t...
A series of p-cymene and cyclopentadienyl Ru(II)-aNHC complexes were synthesized from 2-methylimidaz...
This thesis describes syntheses and catalytic reactivity of several half-sandwich complexes of ruthe...
Tese arquivada ao abrigo da portaria nº 227/2017 de 25 julho.This research study expatiate upon the ...
Novel hydridochlorocarbonyl ruthenium complexes containing N-heterocyclic carbene (NHC) ligands were...
The complex [Cp*RuCl(COD)] reacts with LH2Cl2 (L = bis(3-methylimidazol-2-ylidene)) and LiBun in tet...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Nowadays a number of ruthenium metathesis catalysts have been developed owing to their accessibility...
Nowadays a number of ruthenium metathesis catalysts have been developed owing to their accessibility...
Six olefin metathesis catalysts, based on a common ruthenium precursor featuring a hydroxy-substitut...
The ability to acquire and transfer hydrogen catalytically is fundamental to the development of clea...
N-heterocyclic carbene (NHC) based ruthenium complexes were studied as catalysts for the transfer hy...
Since its discovery by Paul Sabatier, catalytic hydrogenation of unsaturated substrates has become t...
A series of p-cymene and cyclopentadienyl Ru(II)-aNHC complexes were synthesized from 2-methylimidaz...
This thesis describes syntheses and catalytic reactivity of several half-sandwich complexes of ruthe...
Tese arquivada ao abrigo da portaria nº 227/2017 de 25 julho.This research study expatiate upon the ...
Novel hydridochlorocarbonyl ruthenium complexes containing N-heterocyclic carbene (NHC) ligands were...
The complex [Cp*RuCl(COD)] reacts with LH2Cl2 (L = bis(3-methylimidazol-2-ylidene)) and LiBun in tet...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Reactions of carbene complex [Cp(IPr)Ru(pyr)<sub>2</sub>][BF<sub>4</sub>] (<b>6</b>, IPr = 1,3-b...
Nowadays a number of ruthenium metathesis catalysts have been developed owing to their accessibility...
Nowadays a number of ruthenium metathesis catalysts have been developed owing to their accessibility...
Six olefin metathesis catalysts, based on a common ruthenium precursor featuring a hydroxy-substitut...
The ability to acquire and transfer hydrogen catalytically is fundamental to the development of clea...
N-heterocyclic carbene (NHC) based ruthenium complexes were studied as catalysts for the transfer hy...
Since its discovery by Paul Sabatier, catalytic hydrogenation of unsaturated substrates has become t...
A series of p-cymene and cyclopentadienyl Ru(II)-aNHC complexes were synthesized from 2-methylimidaz...