The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold

Homolytic X-H Bond Cleavage at a Gold(III) Hydroxide: Insights into One-Electron Events at Gold

Engbers, Silène
Leach, Isaac F.
Havenith, Remco W.A.
Klein, Johannes E.M.N.

July 2022

C(sp3)-H and O−H bond breaking steps in the oxidation of 1,4-cyclohexadiene and phenol by a Au(III)-...

Reduction of gold(III) to gold(I) by dialkyl sulphides. Evidence for an atom-transfer redox process

G. Annibale
L. Canovese
L. Cattalini
G. Natile

January 1980

A kinetic study of the reduction of gold(III) to gold(I) by dialkyl sulphides, in aqueous mathanol, ...

THE ACTIVATION OF INERT CARBON-OXYGEN AND CARBON-HYDROGEN BONDS BY REACTION WITH METAL ATOMS

KONARSKI, MARK MICHAEL

January 1981

The activation of the carbon-oxygen bonds in ethers and the carbon-hydrogen bonds in alkanes is acco...

The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold

Dupuy, Stephanie
Crawford, Luke
Buehl, Michael
Slawin, Alexandra MZ
Nolan, Steven

January 2012

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transm...

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Dupuy, Stephanie
Crawford, Luke
Buehl, Michael
Slawin, Alexandra M. Z.
Nolan, Steven P.

September 2012

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transm...

A Neutral Gold(III)–Boron Transmetalation

Manuel Hofer (1830463)
Enrique Gomez-Bengoa (1830466)
Cristina Nevado (1530910)

March 2014

The occurrence of direct transmetalation between gold(III) and boron species during gold-catalyzed ...

Heavy metal boryl chemistry: complexes of cadmium, mercury and lead.

Protchenko, AV
Dange, D
Schwarz, AD
Tang, CY
Phillips, N
Mountford, P
Jones, C
Aldridge, S

April 2014

Synthetic routes to the first boryl complexes of cadmium and mercury are reported via transmetallati...

Reactivity of Organogold Compounds with B(C6F5)3: Gold–Boron Transmetalation via σ‑B/π-Au Species

Max M. Hansmann (1264059)
Frank Rominger (63178)
Michael P. Boone (1753792)
Douglas W. Stephan (1264062)
A. Stephen K. Hashmi (1264071)

September 2014

The reactions of gold-acetylides with B(C6F5)3 afford alkynyl bora...

An element through the looking glass: exploring the Au–C, Au–H and Au–O energy landscape

Roşca, D.
Wright, J.
Bochmann, M.

December 2015

Gold, the archetypal “noble metal”, used to be considered of little interest in catalysis. It is now...

Arylgold(I) Complexes from Base-Assisted Transmetalation: Structures, NMR Properties, and Density-Functional Theory Calculations

David V. Partyka (2058070)
Matthias Zeller (526374)
Allen D. Hunter (1668766)
Thomas G. Gray (1269993)

August 2012

The synthesis of gold(I) complexes of the type LAuR (L = PCy3, IPr; R = aryl; IPr = 1,3-...

Transition Metal-Catalysed Intermolecular Reaction of Allenes With Oxygen Nucleophiles: A Perspective

Munoz-Herranz, MP

January 2012

Transition metal catalysed hydroalkoxylation of allenes has received much attention in recent years,...

Facile oxidative addition of aryl iodides to Gold(I) by ligand design: Bending turns on reactivity

Joost, M.
Zeineddine, A.
Estévez, L.
Mallet-Ladeira, S.
Miqueu, K.
Amgoune, A.
Bourissou, D.

January 2014

International audienceThanks to rational ligand design, the first gold(I) complexes to undergo oxida...

New [Au(NHC)(OH)] complexes for silver-free protocols

Patrick, Scott R
Gomez-Suarez, Adrian
Slawin, Alexandra MZ
Nolan, StevenWE060001915761118020022513450000-0001-9024-203577991AC6-987F-11E5-AB6C-4F17B5D1D7B1

January 2014

Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are ratio...

Competitive gold/nickel transmetalation

Demchuk, Mitchell J.
Zurakowski, Joseph A.
Austen, Brady J. H.
Nelson, David J.
Drover, Marcus W.

November 2021

Transmetalation is a key method for the construction of element–element bonds. Here, we disclose the...

Review Open Access

Giorgio Abbiati
Elisabetta Rossi
Elisabetta Rossi

January 2013

License and terms: see end of document. Silver and gold salts and complexes mainly act as soft and c...

Homolytic X-H Bond Cleavage at a Gold(III) Hydroxide: Insights into One-Electron Events at Gold

Engbers, Silène
Leach, Isaac F.
Havenith, Remco W.A.
Klein, Johannes E.M.N.

July 2022

C(sp3)-H and O−H bond breaking steps in the oxidation of 1,4-cyclohexadiene and phenol by a Au(III)-...

Reduction of gold(III) to gold(I) by dialkyl sulphides. Evidence for an atom-transfer redox process

G. Annibale
L. Canovese
L. Cattalini
G. Natile

January 1980

A kinetic study of the reduction of gold(III) to gold(I) by dialkyl sulphides, in aqueous mathanol, ...

THE ACTIVATION OF INERT CARBON-OXYGEN AND CARBON-HYDROGEN BONDS BY REACTION WITH METAL ATOMS

KONARSKI, MARK MICHAEL

January 1981

The activation of the carbon-oxygen bonds in ethers and the carbon-hydrogen bonds in alkanes is acco...

The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold

Dupuy, Stephanie
Crawford, Luke
Buehl, Michael
Slawin, Alexandra MZ
Nolan, Steven

January 2012

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transm...

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

Dupuy, Stephanie
Crawford, Luke
Buehl, Michael
Slawin, Alexandra M. Z.
Nolan, Steven P.

September 2012

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transm...

A Neutral Gold(III)–Boron Transmetalation

Manuel Hofer (1830463)
Enrique Gomez-Bengoa (1830466)
Cristina Nevado (1530910)

March 2014

The occurrence of direct transmetalation between gold(III) and boron species during gold-catalyzed ...

Heavy metal boryl chemistry: complexes of cadmium, mercury and lead.

Protchenko, AV
Dange, D
Schwarz, AD
Tang, CY
Phillips, N
Mountford, P
Jones, C
Aldridge, S

April 2014

Synthetic routes to the first boryl complexes of cadmium and mercury are reported via transmetallati...

Reactivity of Organogold Compounds with B(C6F5)3: Gold–Boron Transmetalation via σ‑B/π-Au Species

Max M. Hansmann (1264059)
Frank Rominger (63178)
Michael P. Boone (1753792)
Douglas W. Stephan (1264062)
A. Stephen K. Hashmi (1264071)

September 2014

The reactions of gold-acetylides with B(C6F5)3 afford alkynyl bora...

An element through the looking glass: exploring the Au–C, Au–H and Au–O energy landscape

Roşca, D.
Wright, J.
Bochmann, M.

December 2015

Gold, the archetypal “noble metal”, used to be considered of little interest in catalysis. It is now...

Arylgold(I) Complexes from Base-Assisted Transmetalation: Structures, NMR Properties, and Density-Functional Theory Calculations

David V. Partyka (2058070)
Matthias Zeller (526374)
Allen D. Hunter (1668766)
Thomas G. Gray (1269993)

August 2012

The synthesis of gold(I) complexes of the type LAuR (L = PCy3, IPr; R = aryl; IPr = 1,3-...

Transition Metal-Catalysed Intermolecular Reaction of Allenes With Oxygen Nucleophiles: A Perspective

Munoz-Herranz, MP

January 2012

Transition metal catalysed hydroalkoxylation of allenes has received much attention in recent years,...

Facile oxidative addition of aryl iodides to Gold(I) by ligand design: Bending turns on reactivity

Joost, M.
Zeineddine, A.
Estévez, L.
Mallet-Ladeira, S.
Miqueu, K.
Amgoune, A.
Bourissou, D.

January 2014

International audienceThanks to rational ligand design, the first gold(I) complexes to undergo oxida...

New [Au(NHC)(OH)] complexes for silver-free protocols

Patrick, Scott R
Gomez-Suarez, Adrian
Slawin, Alexandra MZ
Nolan, StevenWE060001915761118020022513450000-0001-9024-203577991AC6-987F-11E5-AB6C-4F17B5D1D7B1

January 2014

Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are ratio...

Competitive gold/nickel transmetalation

Demchuk, Mitchell J.
Zurakowski, Joseph A.
Austen, Brady J. H.
Nelson, David J.
Drover, Marcus W.

November 2021

Transmetalation is a key method for the construction of element–element bonds. Here, we disclose the...

Review Open Access

Giorgio Abbiati
Elisabetta Rossi
Elisabetta Rossi

January 2013

License and terms: see end of document. Silver and gold salts and complexes mainly act as soft and c...

Homolytic X-H Bond Cleavage at a Gold(III) Hydroxide: Insights into One-Electron Events at Gold

Engbers, Silène
Leach, Isaac F.
Havenith, Remco W.A.
Klein, Johannes E.M.N.

July 2022

C(sp3)-H and O−H bond breaking steps in the oxidation of 1,4-cyclohexadiene and phenol by a Au(III)-...

Reduction of gold(III) to gold(I) by dialkyl sulphides. Evidence for an atom-transfer redox process

G. Annibale
L. Canovese
L. Cattalini
G. Natile

January 1980

A kinetic study of the reduction of gold(III) to gold(I) by dialkyl sulphides, in aqueous mathanol, ...

THE ACTIVATION OF INERT CARBON-OXYGEN AND CARBON-HYDROGEN BONDS BY REACTION WITH METAL ATOMS

KONARSKI, MARK MICHAEL

January 1981

The activation of the carbon-oxygen bonds in ethers and the carbon-hydrogen bonds in alkanes is acco...

The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold

Abstract

Extracted data

The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold

Abstract

Extracted data

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