Positional assembly of enzymes in polymersome nanoreactors for cascade reactions
- Vriezema, Dennis M.
- Garcia, Paula M. L.
- Oltra, Nfflria Sancho
- Hatzakis, Nikos S.
- Kuiper, Suzanne M.
- Nolte, Roeland J. M.
- Rowan, Alan E.
- van Hest, Jan C. M.
Publication date
October 2007
DOI Publisher
Wiley ISSN
1433-7851 Citation count (estimate)
243Abstract
In a good position: Nanoreactors can be constructed by the controlled positioning of glucose oxidase (GOX) and horseradish peroxidase (HRP) within the central water pool and block-copolymer membrane of polymersomes. A one-pot multistep reaction sequence is performed with the nanoreactor in combination with free Candida antarctica lipase B (CALB) in the bulk solution (see picture; ABTS: 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonic acid)). (Chemical Equation Presented
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