Despite a growing interest in two-dimensional polymers, their rational synthesis remains a challenge. The solution-phase synthesis of a two-dimensional polymer is reported. A DNA-based monomer self-assembles into a supramolecular network, which is further converted into the covalently linked two-dimensional polymer by anthracene dimerization. The polymers appear as uniform monolayers, as shown by AFM and TEM imaging. Furthermore, they exhibit a pronounced solvent responsivity. The results demonstrate the value of DNA-controlled self-assembly for the formation of two-dimensional polymers in solution
A grand challenge in materials chemistry is the synthesis of macromolecules and polymers with precis...
Background: One of the goals in the field of structural DNA nanotechnology is the use of DNA to buil...
Nanometer-scale arrays of conducting polymers were prepared on scaffolds of self-assembling DNA modu...
Creation of biocompatible functional materials is an important task in supramolecular chemistry. In ...
The unique self-recognition properties of oligonucleotides laid the foundation of modern DNA nanotec...
Conjugation of functional entities with a specific set of optical, mechanical or biological properti...
The design and synthesis of two-dimensional (2D) polymers is a challenging task, hitherto achieved i...
The predictability of DNA self-assembly is exploited in many nanotechnological approaches. Inspired ...
π-Conjugated (semiconducting) polymers are highly promising materials for applications in various ty...
Inspired by biological polymers, sequence-controlled synthetic polymers are highly promising materia...
Self-assembly of DNA-containing molecules into biocompatible functional materials has attracted cons...
We present a set of DNA supramolecular architectures based on the polymerization of discrete DNA til...
Self-assembly is an abundant process in nature and is vital to many processes in livin...
International audienceThe DNA-guided assembly of biohybrid sequence-defined poly(phosphodiester)s wa...
Nanostructures derived from amphiphilic DNA–polymer conjugates have emerged prominently due to their...
A grand challenge in materials chemistry is the synthesis of macromolecules and polymers with precis...
Background: One of the goals in the field of structural DNA nanotechnology is the use of DNA to buil...
Nanometer-scale arrays of conducting polymers were prepared on scaffolds of self-assembling DNA modu...
Creation of biocompatible functional materials is an important task in supramolecular chemistry. In ...
The unique self-recognition properties of oligonucleotides laid the foundation of modern DNA nanotec...
Conjugation of functional entities with a specific set of optical, mechanical or biological properti...
The design and synthesis of two-dimensional (2D) polymers is a challenging task, hitherto achieved i...
The predictability of DNA self-assembly is exploited in many nanotechnological approaches. Inspired ...
π-Conjugated (semiconducting) polymers are highly promising materials for applications in various ty...
Inspired by biological polymers, sequence-controlled synthetic polymers are highly promising materia...
Self-assembly of DNA-containing molecules into biocompatible functional materials has attracted cons...
We present a set of DNA supramolecular architectures based on the polymerization of discrete DNA til...
Self-assembly is an abundant process in nature and is vital to many processes in livin...
International audienceThe DNA-guided assembly of biohybrid sequence-defined poly(phosphodiester)s wa...
Nanostructures derived from amphiphilic DNA–polymer conjugates have emerged prominently due to their...
A grand challenge in materials chemistry is the synthesis of macromolecules and polymers with precis...
Background: One of the goals in the field of structural DNA nanotechnology is the use of DNA to buil...
Nanometer-scale arrays of conducting polymers were prepared on scaffolds of self-assembling DNA modu...