Addition of tri(2-furyl)phosphine. PFu(3), to [Os-3(CO)(10)(mu-H)(2)] at room temperature gives [HOs3(CO)(10)(PFu(3)) (mu-H)] (1), while in refluxing toluene the same reactants afford [Os-3(CO)(9)(mu(3)-PFu(2)(C4H2O))(mu-H)] (2) resulting from orthometallatation of a furyl ring. Reaction of PFu(3) with [Os-3(CO)(10-n)(NCMe)n] (n = 0, 1, 2) affords the substituted clusters [Os-3(CO)(12-n)(PFu(3))(n)] (n = 1-3) (3-5), the phosphine ligands occupying equatorial position in all cases. Heating [Os-3(CO)(11)(PFu(3))] (3) in refluxing octane gives [Os-3(CO)(9)(mu(3)-PFu)(mu(3)-eta(2)-C4H2O)] (6) which results from both carbon-hydrogen and carbon-phosphorus bond activation and contains both mu(3)-eta(2)-furyne and furylphosphinidene ligands. All ne...
Treatment of the electronically unsaturated cluster Os-3(CO)(8)(mu(3)-eta(2)-Ph2PCH2P(Ph)C6H4)(mu-H)...
The reaction of triosmium alkylidyne cluster [Os3(μ-H)3(CO)9(μ3-CCl)] with excess bis(diphenylphosph...
Reaction of [Os3(CO)11(NCMe)] with bis-diphenylphosphanylethylene sulfide, {Ph2PCH2CH2}2S (PSP), lea...
Reactions of the lightly stabilized triosmium cluster [Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H)] wi...
Reaction of tri(2-furyl) phosphine (PFu(3)) with [Re-2(CO)(10) (n)(NCMe)(n)] (n = 1, 2) at 40 degree...
Treatment of [Fe-3(CO)(12)] with tri(2-furyl)phosphine (PFu(3)) or tri(2-thienyl)phosphine (PTh3) in...
The reaction of 1-(diphenylphosphino)-2-(diphenylphosphito)benzene (PP*) and Os3(CO)10(ACN) has been...
Reaction of [Ru(CO)(9){mu(3-)eta(1),kappa(1),kappa(2)-PhP(C6H4)CH2PPh}] (1) with tri(2-thienyl) phos...
The phenyldi(2-thienyl)phosphine (PhPTh2) complexes [Os-3(CO)(12-n)(PhPTh2)(n)] (n = 1-3) (1-3) have...
This thesis describes the chemistry of the triosmium carbonyl cluster [OS3(CO)10(MECN)2] with phosph...
Reaction of tri(2-furyl)phosphine (PFu3) with [Re2(CO)10−n(NCMe)n] (n = 1, 2) at 40 °C gave the subs...
The synthesis and reactivity of the thiophyne and furyne clusters [Ru-3(CO)(7)(mu-dppm)(mu(3)-eta(2)...
The reaction of 2-[(diphenylphosphino)methyl]-6-methylpyridine (PN) with Os3(CO)12-n(MeCN)n [where n...
Thermal treatment of [OS3(CO)(12)] with diphenyl(2-thienyl)phosphane, Ph(2)p(C4H3S), results in the ...
The coordination mode of dppf {dppf = 1,1'-bis(diphenylphosphino)ferrocene} at triosmium and triruth...
Treatment of the electronically unsaturated cluster Os-3(CO)(8)(mu(3)-eta(2)-Ph2PCH2P(Ph)C6H4)(mu-H)...
The reaction of triosmium alkylidyne cluster [Os3(μ-H)3(CO)9(μ3-CCl)] with excess bis(diphenylphosph...
Reaction of [Os3(CO)11(NCMe)] with bis-diphenylphosphanylethylene sulfide, {Ph2PCH2CH2}2S (PSP), lea...
Reactions of the lightly stabilized triosmium cluster [Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H)] wi...
Reaction of tri(2-furyl) phosphine (PFu(3)) with [Re-2(CO)(10) (n)(NCMe)(n)] (n = 1, 2) at 40 degree...
Treatment of [Fe-3(CO)(12)] with tri(2-furyl)phosphine (PFu(3)) or tri(2-thienyl)phosphine (PTh3) in...
The reaction of 1-(diphenylphosphino)-2-(diphenylphosphito)benzene (PP*) and Os3(CO)10(ACN) has been...
Reaction of [Ru(CO)(9){mu(3-)eta(1),kappa(1),kappa(2)-PhP(C6H4)CH2PPh}] (1) with tri(2-thienyl) phos...
The phenyldi(2-thienyl)phosphine (PhPTh2) complexes [Os-3(CO)(12-n)(PhPTh2)(n)] (n = 1-3) (1-3) have...
This thesis describes the chemistry of the triosmium carbonyl cluster [OS3(CO)10(MECN)2] with phosph...
Reaction of tri(2-furyl)phosphine (PFu3) with [Re2(CO)10−n(NCMe)n] (n = 1, 2) at 40 °C gave the subs...
The synthesis and reactivity of the thiophyne and furyne clusters [Ru-3(CO)(7)(mu-dppm)(mu(3)-eta(2)...
The reaction of 2-[(diphenylphosphino)methyl]-6-methylpyridine (PN) with Os3(CO)12-n(MeCN)n [where n...
Thermal treatment of [OS3(CO)(12)] with diphenyl(2-thienyl)phosphane, Ph(2)p(C4H3S), results in the ...
The coordination mode of dppf {dppf = 1,1'-bis(diphenylphosphino)ferrocene} at triosmium and triruth...
Treatment of the electronically unsaturated cluster Os-3(CO)(8)(mu(3)-eta(2)-Ph2PCH2P(Ph)C6H4)(mu-H)...
The reaction of triosmium alkylidyne cluster [Os3(μ-H)3(CO)9(μ3-CCl)] with excess bis(diphenylphosph...
Reaction of [Os3(CO)11(NCMe)] with bis-diphenylphosphanylethylene sulfide, {Ph2PCH2CH2}2S (PSP), lea...