Insertion of carbon dioxide into (PCP)Pd-II-Me bonds
- Johansson, Roger
- Jarenmark, Martin
- Wendt, Ola
Publication date
January 2005
DOI Publisher
American Chemical Society (ACS) ISSN
0276-7333 Citation count (estimate)
58Abstract
A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene
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