We used temperature programmed reaction spectroscopy (TPRS) and synchrotron-radiation based photoelectron spectroscopy (PES) to investigate the adsorption and oxidation of methanol (CH3OH) on Tb2O3(111) and TbO2(111) thin films grown on Pt(111). We find that methanol mainly desorbs from the Tb2O3 surface through both molecular and recombinative processes, and that a relatively small amount of adsorbed methanol (< 20%) dehydrogenates to CH2O and H2O with these species desorbing between about 160 and 300 K. Oxidation of the terbia film enhances the surface reactivity as ~50% of the adsorbed methanol on TbO2 oxidizes to mainly CH2O and water as well as CO2 that desorbs near 600 K during TPRS. Quantification of the product yields suggests that ...
Photocatalysis of methanol (CH<sub>3</sub>OH) on anatase (A)-TiO<sub>2</sub>(101) has been investiga...
A broadband infrared surface sum frequency generation vibrational spectroscopy (SFG-VS) and an in si...
The adsorbate species present during partial oxidation of methanol on a Cu(110) surface have been in...
We investigated the adsorption and reaction of methanol on continuous and discontinuous films of sam...
The adsorption, decompn., and oxidn. of methanol (CH3OH) has been studied on Ir(111) using temp.-pro...
A detailed study of the methanol chemisorption and oxidation processes on oxide surfaces allowed the...
The partial oxidation of methanol to formaldehyde on well-ordered thin V2O5(001)films supported on A...
Well ordered V2O3(0001) layers may be grown on Au(111) surfaces. These films are terminated by a lay...
Molecular and dissociative forms of adsorbed methanol were prepared on the rutile TiO<sub>2</sub>(11...
We studied the photocatalytic reaction of methanol on the TiO2(110) surface in situ by surface sum f...
Ambient pressure X-ray photoelectron spectroscopy (APXPS) has been used to study the initial stages ...
Decomposition and oxidation of methanol on Pt(111) have been examined between 300 and 650 K in the m...
Although methanol on rutile TiO2(110) has been widely investigated under ultrahigh vacuum (UHV) cond...
We have conducted a series of temperature programmed desorption (TPD) experiments to study the photo...
As a cocatalyst, Pt is well-known for accepting photoexcited electrons and lowering the overpotentia...
Photocatalysis of methanol (CH<sub>3</sub>OH) on anatase (A)-TiO<sub>2</sub>(101) has been investiga...
A broadband infrared surface sum frequency generation vibrational spectroscopy (SFG-VS) and an in si...
The adsorbate species present during partial oxidation of methanol on a Cu(110) surface have been in...
We investigated the adsorption and reaction of methanol on continuous and discontinuous films of sam...
The adsorption, decompn., and oxidn. of methanol (CH3OH) has been studied on Ir(111) using temp.-pro...
A detailed study of the methanol chemisorption and oxidation processes on oxide surfaces allowed the...
The partial oxidation of methanol to formaldehyde on well-ordered thin V2O5(001)films supported on A...
Well ordered V2O3(0001) layers may be grown on Au(111) surfaces. These films are terminated by a lay...
Molecular and dissociative forms of adsorbed methanol were prepared on the rutile TiO<sub>2</sub>(11...
We studied the photocatalytic reaction of methanol on the TiO2(110) surface in situ by surface sum f...
Ambient pressure X-ray photoelectron spectroscopy (APXPS) has been used to study the initial stages ...
Decomposition and oxidation of methanol on Pt(111) have been examined between 300 and 650 K in the m...
Although methanol on rutile TiO2(110) has been widely investigated under ultrahigh vacuum (UHV) cond...
We have conducted a series of temperature programmed desorption (TPD) experiments to study the photo...
As a cocatalyst, Pt is well-known for accepting photoexcited electrons and lowering the overpotentia...
Photocatalysis of methanol (CH<sub>3</sub>OH) on anatase (A)-TiO<sub>2</sub>(101) has been investiga...
A broadband infrared surface sum frequency generation vibrational spectroscopy (SFG-VS) and an in si...
The adsorbate species present during partial oxidation of methanol on a Cu(110) surface have been in...