We report on extending hard X-ray emission spectroscopy (XES) along with resonant inelastic X-ray scattering (RIXS) to study ultrafast phenomena in a pump-probe scheme at MHz repetition rates. The investigated systems include low-spin (LS) Fe-II complex compounds, where optical pulses induce a spin-state transition to their (sub)nanosecond-lived high-spin (HS) state. Time-resolved XES clearly reflects the spin-state variations with very high signal-to-noise ratio, in agreement with HS-LS difference spectra measured at thermal spin crossover, and reference HS-LS systems in static experiments, next to multiplet calculations. The 1s2p RIXS, measured at the Fe Is pre-edge region, shows variations after laser excitation, which are consistent wit...
The past two decades have seen rapid developments in short-pulse X-ray sources, which have enabled t...
We have studied the photoinduced low spin (LS) to high spin (HS) conversion of [Fe(bipy)3]2+ in aque...
The past two decades have seen rapid developments in short-pulse X-ray sources, which have enabled t...
We report on extending hard X-ray emission spectroscopy (XES) along with resonant inelastic X-ray sc...
We report on extending hard X-ray emission spectroscopy (XES) along with resonant inelastic X-ray sc...
International audienceX-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (∼10(12...
X-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (1012 photons) pulses of hard...
X-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (similar to 10(12) photons) p...
X-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (∼1012 photons) pulses of har...
Experimental tools capable of monitoring both atomic and electronic structure on ultrafast (femtosec...
Understanding the initial steps during ultrafast molecular reactions involving large spin state chan...
Ultrafast pump-probe spectroscopy within the X-ray regime is now possible owing to the devel- opment...
For probing the nature of spin-state switching in spin-crossover molecules adsorbed on surfaces, x-...
We report the first time-resolved soft x-ray measurements of solvated transition-metal complexes. L-...
We have studied the photoinduced low spin (LS) to high spin (HS) conversion of [Fe(bipy)3]2+ in aque...
The past two decades have seen rapid developments in short-pulse X-ray sources, which have enabled t...
We have studied the photoinduced low spin (LS) to high spin (HS) conversion of [Fe(bipy)3]2+ in aque...
The past two decades have seen rapid developments in short-pulse X-ray sources, which have enabled t...
We report on extending hard X-ray emission spectroscopy (XES) along with resonant inelastic X-ray sc...
We report on extending hard X-ray emission spectroscopy (XES) along with resonant inelastic X-ray sc...
International audienceX-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (∼10(12...
X-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (1012 photons) pulses of hard...
X-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (similar to 10(12) photons) p...
X-ray free electron lasers (XFELs) deliver short (<100 fs) and intense (∼1012 photons) pulses of har...
Experimental tools capable of monitoring both atomic and electronic structure on ultrafast (femtosec...
Understanding the initial steps during ultrafast molecular reactions involving large spin state chan...
Ultrafast pump-probe spectroscopy within the X-ray regime is now possible owing to the devel- opment...
For probing the nature of spin-state switching in spin-crossover molecules adsorbed on surfaces, x-...
We report the first time-resolved soft x-ray measurements of solvated transition-metal complexes. L-...
We have studied the photoinduced low spin (LS) to high spin (HS) conversion of [Fe(bipy)3]2+ in aque...
The past two decades have seen rapid developments in short-pulse X-ray sources, which have enabled t...
We have studied the photoinduced low spin (LS) to high spin (HS) conversion of [Fe(bipy)3]2+ in aque...
The past two decades have seen rapid developments in short-pulse X-ray sources, which have enabled t...