We present the first Herschel PACS and SPIRE results of the Vela C molecular complex in the far-infrared and submillimetre regimes at 70, 160, 250, 350, and 500 μm, spanning the peak of emission of cold prestellar or protostellar cores. Column density and multi-resolution analysis (MRA) differentiates the Vela C complex into five distinct sub-regions. Each sub-region displays differences in their column density and temperature probability distribution functions (PDFs), in particular, the PDFs of the “Centre-Ridge” and “South-Nest” sub-regions appear in stark contrast to each other. The Centre-Ridge displays a bimodal temperature PDF representative of hot gas surrounding the HII region RCW 36 and the cold neighbouring filaments, whilst the ...