Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex
- Arnold, Polly L.
- Marr, Isobel A.
- Zlatogorsky, Sergey
- Bellabarba, Ronan
- Tooze, Robert P.
DOIAbstract
A Sc NHC complex readily activates three equivalents of CO2 showing ‘Frustrated Lewis Pair’ type reactivity with each metal–carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed. Graphical abstract: Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene comple
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