AbstractThe Non-Aqueous Solvent (NAS) CO2 Capture Process is being developed as an advanced, next-generation post-combustion capture technology for CO2 removal from power generation and industrial flue gas streams. The core of the NAS process has been the development of a family of CO2-selective NASs that have the potential to substantially reduce the thermal regeneration energy demand associated with solvent regeneration to ∼ 2,000 kJt/kg of CO2 captured. This paper discusses our rationale for selecting a NAS platform and provides results from the physical and thermodynamic characterization of the NASs, lab-scale testing results, and an update on our efforts to address specific process design challenges related to NAS processes for evaluat...